Ontology highlight
ABSTRACT:
SUBMITTER: Qian Y
PROVIDER: S-EPMC3663892 | biostudies-literature | 2013 Apr
REPOSITORIES: biostudies-literature
Organic letters 20130311 7
A highly regio- and diastereoselective synthesis of bicyclic pyrazolidinone derivatives by rhodium(II) acetate catalyzed [3 + 3]-annulation with enoldiazoacetates and azomethine imines has been achieved in high yield. A vinylogous reaction of the metal enol carbene with the azomethine imine initiates [3 + 3]-cycloaddition, whereas reaction at the carbene center effects N-N-cleavage of the azomethine imine. ...[more]