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Crystal structure of bis-(benzyl-amine-?N)[5,10,15,20-tetra-kis-(4-chloro-phen-yl)porphyrinato-?(4) N]iron(II) n-hexane monosolvate.

ABSTRACT: In the title compound, [Fe(II)(C44H24Cl4N4)(C6H5CH2NH2)2]·C6H14 or [Fe(II)(TPP-Cl)(BzNH2)2]·n-hexane [where TPP-Cl and BzNH2 are 5,10,15,20-tetra-kis-(4-chloro-phen-yl)porphyrinate and benzyl-amine ligands, respectively], the Fe(II) cation lies on an inversion centre and is octa-hedrally coordinated by the four pyrrole N atoms of the porphyrin ligand in the equatorial plane and by two amine N atoms of the benzyl-amine ligand in the axial sites. The crystal structure also contains one inversion-symmetric n-hexane solvent mol-ecule per complex mol-ecule. The average Fe-Npyrrole bond length [1.994?(3)?Å] indicates a low-spin complex. The crystal packing is sustained by N-H?Cl and C-H?Cl hydrogen-bonding inter-actions and by C-H?? inter-molecular inter-actions, leading to a three-dimensional network structure.

SUBMITTER: Dhifaoui S

PROVIDER: S-EPMC4704743 | biostudies-literature | 2016 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(benzyl-amine-κN)[5,10,15,20-tetra-kis-(4-chloro-phen-yl)porphyrinato-κ(4) N]iron(II) n-hexane monosolvate.

Dhifaoui Selma S Harhouri Wafa W Bujacz Anna A Nasri Habib H

Acta crystallographica. Section E, Crystallographic communications 20160101 Pt 1

In the title compound, [Fe(II)(C44H24Cl4N4)(C6H5CH2NH2)2]·C6H14 or [Fe(II)(TPP-Cl)(BzNH2)2]·n-hexane [where TPP-Cl and BzNH2 are 5,10,15,20-tetra-kis-(4-chloro-phen-yl)porphyrinate and benzyl-amine ligands, respectively], the Fe(II) cation lies on an inversion centre and is octa-hedrally coordinated by the four pyrrole N atoms of the porphyrin ligand in the equatorial plane and by two amine N atoms of the benzyl-amine ligand in the axial sites. The crystal structure also contains one inversion-s ...[more]

PMID: 26870596

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