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[5,10,15,20-Tetra-kis(4-meth-oxy-phen-yl)porphyrinato-?N,N',N'',N'''](trifluoro-methane-sulfonato-?O)-iron(III).

ABSTRACT: The title compound, [Fe(CF(3)O(3)S)(C(48)H(36)N(4)O(4))], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The Fe(III) atom is displaced by 0.40?(1)?Å towards the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe-N(p) distance is 2.044?(2)?Å and the Fe-O distance is 2.001?(2)?Å.

SUBMITTER: Xu N

PROVIDER: S-EPMC3051595 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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[5,10,15,20-Tetra-kis(4-meth-oxy-phen-yl)porphyrinato-κN,N',N'',N'''](trifluoro-methane-sulfonato-κO)-iron(III).

Xu Nan N Powell Douglas R DR Richter-Addo George B GB

Acta crystallographica. Section E, Structure reports online 20110129 Pt 2

The title compound, [Fe(CF(3)O(3)S)(C(48)H(36)N(4)O(4))], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The Fe(III) atom is displaced by 0.40 (1) Å towards the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe-N(p) distance is 2.044 (2) Å and the Fe-O distance is 2.001 (2) Å. ...[more]

PMID: 21522918

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