Ontology highlight
ABSTRACT:
SUBMITTER: Xu N
PROVIDER: S-EPMC3051595 | biostudies-literature | 2011 Jan
REPOSITORIES: biostudies-literature
Xu Nan N Powell Douglas R DR Richter-Addo George B GB
Acta crystallographica. Section E, Structure reports online 20110129 Pt 2
The title compound, [Fe(CF(3)O(3)S)(C(48)H(36)N(4)O(4))], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The Fe(III) atom is displaced by 0.40 (1) Å towards the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe-N(p) distance is 2.044 (2) Å and the Fe-O distance is 2.001 (2) Å. ...[more]