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High Coke-Resistance Pt/Mg1-xNixO Catalyst for Dry Reforming of Methane.

ABSTRACT: A highly active and stable nano structured Pt/Mg1-xNixO catalysts was developed by a simple co-precipitation method. The obtained Pt/Mg1-xNixO catalyst exhibited cubic structure nanocatalyst with a size of 50-80 nm and realized CH4 and CO2 conversions as high as 98% at 900°C with excellent stability in the dry reforming of methane. The characterization of catalyst was performed using various kinds of analytical techniques including XRD, BET, XRF, TPR-H2, TGA, TEM, FESEM, FT-IR, and XPS analyses. Characterization of spent catalyst further confirms that Pt/Mg1-xNixO catalyst has high coke-resistance for dry reforming. Thus, the catalyst demonstrated in this study, offers a promising catalyst for resolving the dilemma between dispersion and reducibility of supported metal, as well as activity and stability during high temperature reactions.

SUBMITTER: Al-Doghachi FA

PROVIDER: S-EPMC4706417 | biostudies-literature | 2016

REPOSITORIES: biostudies-literature

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High Coke-Resistance Pt/Mg1-xNixO Catalyst for Dry Reforming of Methane.

Al-Doghachi Faris A J FA Islam Aminul A Zainal Zulkarnain Z Saiman Mohd Izham MI Embong Zaidi Z Taufiq-Yap Yun Hin YH

PloS one 20160108 1

A highly active and stable nano structured Pt/Mg1-xNixO catalysts was developed by a simple co-precipitation method. The obtained Pt/Mg1-xNixO catalyst exhibited cubic structure nanocatalyst with a size of 50-80 nm and realized CH4 and CO2 conversions as high as 98% at 900°C with excellent stability in the dry reforming of methane. The characterization of catalyst was performed using various kinds of analytical techniques including XRD, BET, XRF, TPR-H2, TGA, TEM, FESEM, FT-IR, and XPS analyses. ...[more]

PMID: 26745623

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