Browse
Submit Data
Databases
API
Help

Dataset Information

16 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Nanoporous Nickel Composite Catalyst for the Dry Reforming of Methane.

ABSTRACT: The development of efficient catalysts with high activities and durabilities for use in the dry reforming of methane (DRM) is desirable but challenging. We report the development of a nanoporous nickel composite (nanoporous Ni/Y₂O₃) via a facile one-step dealloying technique, for use in the DRM. Focusing on the low-temperature DRM, our composite possessed remarkable activity and durability against coking compared with conventional particle-based Ni catalysts. This was attributed to the aluminum oxides present on the Ni surface, which suppress pore coarsening. In addition, the inert bundled Y₂O₃ nanowires are suitable for use as substrates for nanoporous Ni.

SUBMITTER: Fujita T

PROVIDER: S-EPMC6643422 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Nanoporous Nickel Composite Catalyst for the Dry Reforming of Methane.

Fujita Takeshi T Peng Xiaobo X Yamaguchi Akira A Cho Yohei Y Zhang Yongzheng Y Higuchi Kimitaka K Yamamoto Yuta Y Tokunaga Tomoharu T Arai Shigeo S Miyauchi Masahiro M Abe Hideki H

ACS omega 20181205 12

The development of efficient catalysts with high activities and durabilities for use in the dry reforming of methane (DRM) is desirable but challenging. We report the development of a nanoporous nickel composite (nanoporous Ni/Y<sub>2</sub>O<sub>3</sub>) via a facile one-step dealloying technique, for use in the DRM. Focusing on the low-temperature DRM, our composite possessed remarkable activity and durability against coking compared with conventional particle-based Ni catalysts. This was attri ...[more]

PMID: 31458296

Similar Datasets

NiYAl-Derived Nanoporous Catalysts for Dry Reforming of Methane.

Project description:Dry reforming of methane can be used for suppressing the rapid growth of greenhouse gas emissions. However, its practical implementation generally requires high temperatures. In this study, we report an optimal catalyst for low-temperature dry reforming of methane with high carbon coking resistance synthesized from NiYAl alloy. A facile two-step process consisting of preferential oxidation and leaching was utilized to produce structurally robust nanoporous Ni metal and Y oxides from NiYAl4. The catalyst exhibited an optimal carbon balance (0.96) close to the ideal value of 1.0, indicating the optimized dry reforming pathway. This work proposes a facile route of the structural control of active metal/oxide sites for realizing highly active catalysts with long-term durability.

| S-EPMC7254345 | biostudies-literature

Promotional effect of magnesium oxide for a stable nickel-based catalyst in dry reforming of methane.

Project description:The generation of synthesis gas (hydrogen and carbon monoxide mixture) from two global warming gases of carbon dioxide and methane via dry reforming is environmentally crucial and for the chemical industry as well. Herein, magnesium-promoted NiO supported on mesoporous zirconia, 5Ni/xMg-ZrO2 (x = 0, 3, 5, 7 wt%) were prepared by wet impregnation method and then were tested for syngas production via dry reforming of methane. The reaction temperature at 800 °C was found more catalytically active than that at 700 °C due to the endothermic feature of reaction which promotes efficient CH4 catalytic decomposition over Ni and Ni-Zr interface as confirmed by CH4-TSPR experiment. NiO-MgO solid solution interacted with ZrO2 support was found crucial and the reason for high CH4 and CO2 conversions. The highest catalyst stability of the 5Ni/3Mg-ZrO2 catalyst was explained by the ability of CO2 to partially oxidize the carbon deposit over the surface of the catalyst. A mole ratio of hydrogen to carbon monoxide near unity (H2/CO ~ 1) was obtained over 5Ni/ZrO2 and 5Ni/5Mg-ZrO2, implying the important role of basic sites. Our approach opens doors for designing cheap and stable dry reforming catalysts from two potent greenhouse gases which could be of great interest for many industrial applications, including syngas production and other value-added chemicals.

| S-EPMC7431551 | biostudies-literature

Effect of Holmium Oxide Loading on Nickel Catalyst Supported on Yttria-Stabilized Zirconia in Methane Dry Reforming.

Project description:The carbon dioxide reforming of methane has attracted attention from researchers owing to its possibility of both mitigating the hazards of reactants and producing useful chemical intermediates. In this framework, the activity of the nickel-based catalysts, supported by yttria-stabilized zirconia and promoted with holmium oxide (Ho2O3), was assessed in carbon dioxide reforming of methane at 800 °C. The catalysts were characterized by N2-physisorption, H2 temperature-programmed reduction, temperature-programmed desorption of CO2, X-ray diffraction, scanning electron microscopy (SEM) together with energy-dispersive X-ray spectroscopy, transmission electron microscopy (TEM), and thermogravimetric analysis (TGA) techniques. The effect of holmium oxide weight percent loading (0.0, 1.0, 2.0, 3,0, 4.0, and 5.0 wt %) was examined owing to its impact on the developed catalysts. The optimum loading of Ho2O3 was found to be 4.0 wt %, where the methane and carbon dioxide conversions were 85 and 91%, respectively. The nitrogen adsorption-desorption isotherms specified the mesoporous aspect of the catalysts, while the SEM images displayed a morphology of agglomerated, porous particles. The TEM images of the spent catalyst displayed the formation of multiwalled carbon nanotubes. TGA of the 4.0 wt % of Ho2O3 catalyst, experimented over 7-hour time-on-stream, displayed little weight loss (<14.0 wt %) owing to carbon formation, indicating the good resistance of the catalyst to carbon accumulation due to the enhancing ability of Ho2O3 and its adjustment of the support.

| S-EPMC9730481 | biostudies-literature

Atomically dispersed nickel as coke-resistant active sites for methane dry reforming.

Project description:Dry reforming of methane (DRM) is an attractive route to utilize CO2 as a chemical feedstock with which to convert CH4 into valuable syngas and simultaneously mitigate both greenhouse gases. Ni-based DRM catalysts are promising due to their high activity and low cost, but suffer from poor stability due to coke formation which has hindered their commercialization. Herein, we report that atomically dispersed Ni single atoms, stabilized by interaction with Ce-doped hydroxyapatite, are highly active and coke-resistant catalytic sites for DRM. Experimental and computational studies reveal that isolated Ni atoms are intrinsically coke-resistant due to their unique ability to only activate the first C-H bond in CH4, thus avoiding methane deep decomposition into carbon. This discovery offers new opportunities to develop large-scale DRM processes using earth abundant catalysts.

| S-EPMC6858327 | biostudies-literature

High Coke-Resistance Pt/Mg1-xNixO Catalyst for Dry Reforming of Methane.

Project description:A highly active and stable nano structured Pt/Mg1-xNixO catalysts was developed by a simple co-precipitation method. The obtained Pt/Mg1-xNixO catalyst exhibited cubic structure nanocatalyst with a size of 50-80 nm and realized CH4 and CO2 conversions as high as 98% at 900°C with excellent stability in the dry reforming of methane. The characterization of catalyst was performed using various kinds of analytical techniques including XRD, BET, XRF, TPR-H2, TGA, TEM, FESEM, FT-IR, and XPS analyses. Characterization of spent catalyst further confirms that Pt/Mg1-xNixO catalyst has high coke-resistance for dry reforming. Thus, the catalyst demonstrated in this study, offers a promising catalyst for resolving the dilemma between dispersion and reducibility of supported metal, as well as activity and stability during high temperature reactions.

| S-EPMC4706417 | biostudies-literature

Dry reforming of methane over nickel supported on Nd-ceria: enhancement of the catalytic properties and coke resistance.

Project description:Nickel (5 wt%) supported on Nd-doped ceria was studied as catalysts in the DRM reaction at stoichiometric conditions in the range of 600-800 °C. Ce1-x Nd x O2-δ supports with different Nd contents (x = 0, 0.05, 0.1 and 0.2) were successfully synthesized. The role of oxygen vacancies by the incorporation of Nd3+ into the ceria lattice was investigated. These species were quantified by XRD and Raman spectroscopy, showing a linear dependence as a function of Nd content. Ni/Nd-ceria catalysts were prepared by wet impregnation. Although formation of oxygen vacancies, as well as microstructural features of the support (smaller crystallite sizes, higher surface area, and developed mesoporous structure) were improved as a function of the Nd content, no significant differences were observed in the catalytic properties of Ni/Nd-ceria in the DRM reaction. Despite this, compared to undoped ceria, all the Nd-doped CeO2 catalysts present an enhanced activity and stability, and the best catalytic performance was observed in the Ni/Ce0.95Nd0.05O2-δ sample. Quantification of carbon residues in spent catalysts showed, as expected, lower amounts in the Ni/Nd-ceria samples; nevertheless, among them, the catalyst with the higher amount of oxygen vacancies, is the one with the higher carbon residues. Incorporation of Nd in ceria changes the acid/base properties, diminishing the gasification capacity of the carbonaceous species. These results emphasize that the activity and stability in the Ni/Nd-ceria catalysts for the DRM reaction depend on two key factors, the redox and the acid/base properties of the CeO2 supports, offering insights about the necessary and adequate balance between these properties.

| S-EPMC9056702 | biostudies-literature

In Situ X-ray Microscopy Reveals Particle Dynamics in a NiCo Dry Methane Reforming Catalyst under Operating Conditions.

Project description:Herein, we report the synthesis of a ?-Al2O3-supported NiCo catalyst for dry methane reforming (DMR) and study the catalyst using in situ scanning transmission X-ray microscopy (STXM) during the reduction (activation step) and under reaction conditions. During the reduction process, the NiCo alloy particles undergo elemental segregation with Co migrating toward the center of the catalyst particles and Ni migrating to the outer surfaces. Under DMR conditions, the segregated structure is maintained, thus hinting at the importance of this structure to optimal catalytic functions. Finally, the formation of Ni-rich branches on the surface of the particles is observed during DMR, suggesting that the loss of Ni from the outer shell may play a role in the reduced stability and hence catalyst deactivation. These findings provide insights into the morphological and electronic structural changes that occur in a NiCo-based catalyst during DMR. Further, this study emphasizes the need to study catalysts under operating conditions in order to elucidate material dynamics during the reaction.

| S-EPMC7295368 | biostudies-literature

Ultrathin Washcoat and Very Low Loading Monolithic Catalyst with Outstanding Activity and Stability in Dry Reforming of Methane.

Project description:A Ni/CeO2/ZrO2 catalyst with improved redox properties has been washcoated onto a honeycomb cordierite monolith in the form of a nonconventional alumina-catalyst layer, just a few nanometers thick. In spite of the very low active phase loading, the monolith depicts outstanding performance in dry reforming of methane, both in terms of activity, with values reaching the thermodynamic limit already at 750 °C, even under extreme Weight Hourly Space Velocities (WHSV 115-346 L·g-1·h-1), as well as in terms of stability during prolonged Time on Stream (TOS 24-48 h).

| S-EPMC7152993 | biostudies-literature

Alumina-Magnesia-Supported Ni for Hydrogen Production via the Dry Reforming of Methane: A Cost-Effective Catalyst System.

Project description:5Ni/MgO and 5Ni/γAl2O3 are pronounced in the line of cheap catalyst systems for the dry reforming of methane. However, the lower reducibility of 5Ni/MgO and the significant coke deposition over 5Ni/γAl2O3 limit their applicability as potential DRM catalysts. The mixing capacity of MgO and Al2O3 may overcome these limitations without increasing the catalyst cost. Herein, a 5Ni/xMg(100 - x)Al (x = 0, 20, 30, 60, 70, and 100 wt. %) catalyst system is prepared, investigated, and characterized with X-ray diffraction, surface area and porosity measurements, H2-temperature programmed reduction, UV-Vis-IR spectroscopy, Raman spectroscopy, thermogravimetry, and transmission electron microscopy. Upon the addition of 20 wt. % MgO into the Al2O3 support, 5Ni/20Mg80Al is expanded and carries both stable Ni sites (derived through the reduction of NiAl2O4) and a variety of CO2-interacting species. CH4 decomposition at Ni sites and the potential oxidation of carbon deposits by CO2-interacting species over 5Ni/20Mg80Al results in a higher 61% H2-yield (against ~55% H2-yield over 5Ni/γAl2O3) with an excellent carbon-resistant property. In the major magnesia support system, the 5Ni/60Mg40Al catalyst carries stable Ni sites derived from MgNiO2 and "strongly interacted NiO-species". The H2-yield over the 5Ni/60Mg40Al catalyst moves to 71%, even against a high coke deposition, indicating fine tuning between the carbon formation and diffusion rates. Ni dispersed over magnesia-alumina with weight ratios of 7/3 and 3/7 exhibit good resistance to coke. Weight ratios of 2/8 and 7/3 contain an adequate amount of reducible and CO2-interactive species responsible for producing over 60% of H2-yield. Weight ratio 6/4 has a proper coke diffusion mechanism in addition to achieving a maximum of 71% H2-yield.

| S-EPMC10708042 | biostudies-literature

Thermodynamic assessment of the stability of bulk and nanoparticulate cobalt and nickel during dry and steam reforming of methane.

Project description:The high reaction temperatures during steam and dry reforming of methane inevitably entail catalyst deactivation. Evaluation of the feasibility or potentially relevant mechanisms at play is of utmost importance to develop highly active and stable catalysts. Herein, various oxidation reactions of bulk-sized nickel and cobalt to the corresponding metal oxide or in the presence of a metal oxide carrier are evaluated thermodynamically and linked to approximated conditions during methane reforming. In particular cobalt aluminate, as well as cobalt or nickel titanates are likely to form. As oxidation to bulk-sized metal oxide is unlikely, a thermodynamic analysis of metallic nanoparticles was performed to calculate the size dependent stability against oxidation to nickel oxide or cobalt oxide in water and carbon dioxide-rich environments. The calculations indicate that nickel nanoparticles >3 nm and cobalt nanoparticles >10 nm are expected to withstand oxidation during steam and dry reforming of methane with stoichiometric feed compositions and methane conversion levels >10% at temperatures up to 1100 and 900 °C, respectively. Lastly, the reduced thermal stability of nanoparticles due to melting point suppression was assessed, leading to similar recommendations concerning minimum particle sizes.

| S-EPMC8132427 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data