Ontology highlight
ABSTRACT:
SUBMITTER: Yuan YA
PROVIDER: S-EPMC4719780 | biostudies-literature | 2016 Jan
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20151123 2
Reported herein is a new iron-catalyzed diastereoselective olefin diazidation reaction which occurs at room temperature (1-5 mol% of catalysts and d.r. values of up to >20:1). This method tolerates a broad range of both unfunctionalized and highly functionalized olefins, including those that are incompatible with existing methods. It also provides a convenient approach to vicinal primary diamines as well as other synthetically valuable nitrogen-containing building blocks which are difficult to o ...[more]