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Crystal structure of N'-[bis-(ethyl-sulfan-yl)methyl-idene]-2-hy-droxy-4-meth-oxy-benzohydrazide.

ABSTRACT: In the title compound, C13H18N2O3S2, the amide group is in the plane of the -benzoyl ring with a C-N-N-C torsion angle of 177.63?(12)°. The two di-thio-ate groups are in an anti conformation [torsion angles = 173.68?(8) and -9.98?(10)°]. An intra-molecular N-H?O hydrogen bond is observed. In the crystal, an O-H?O hydrogen bond and a weak C-H?O contact involving the same acceptor atom generate an S(6) ring motif and give rise to chains along [010].

SUBMITTER: Nath P

PROVIDER: S-EPMC4719926 | biostudies-literature | 2015 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of N'-[bis-(ethyl-sulfan-yl)methyl-idene]-2-hy-droxy-4-meth-oxy-benzohydrazide.

Nath Paras P Bharty Manoj K MK Chaurasia Rahul R Kumari Sanyucta S Gupta Sushil K SK

Acta crystallographica. Section E, Crystallographic communications 20151121 Pt 12

In the title compound, C13H18N2O3S2, the amide group is in the plane of the -benzoyl ring with a C-N-N-C torsion angle of 177.63 (12)°. The two di-thio-ate groups are in an anti conformation [torsion angles = 173.68 (8) and -9.98 (10)°]. An intra-molecular N-H⋯O hydrogen bond is observed. In the crystal, an O-H⋯O hydrogen bond and a weak C-H⋯O contact involving the same acceptor atom generate an S(6) ring motif and give rise to chains along [010]. ...[more]

PMID: 26870554

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