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N'-[Bis(benzyl-sulfan-yl)methyl-idene]-4-meth-oxy-benzohydrazide.


ABSTRACT: In the title compound, C(23)H(22)N(2)O(2)S(2), the dihedral angles between the 4-meth-oxy-substituted phenyl ring and the other two phenyl rings are 84.4?(4) and 77.7?(1)°, respectively, while the dihedral angle between the two phenyl rings is 57.5?(2)°. The amino group is not involved in an N-H hydrogen bond. The crystal packing is established by inter-molecular C-H?O packing inter-actions involving a relatively rare weak three-center hydrogen bond between the keto O atom and H atoms of the two nearby phenyl rings, which link the mol-ecules into chains running along the a axis. Additional weak inter-molecular hydrogen-bond inter-actions between the 4-meth-oxy O atom and one of the phenyl rings and provide added stability to the crystal packing.

SUBMITTER: Jasinski JP 

PROVIDER: S-EPMC3007250 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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N'-[Bis(benzyl-sulfan-yl)methyl-idene]-4-meth-oxy-benzohydrazide.

Jasinski Jerry P JP   Butcher Ray J RJ   Kushawaha S K SK   Bharty M K MK   Singh N K NK  

Acta crystallographica. Section E, Structure reports online 20100703 Pt 8


In the title compound, C(23)H(22)N(2)O(2)S(2), the dihedral angles between the 4-meth-oxy-substituted phenyl ring and the other two phenyl rings are 84.4 (4) and 77.7 (1)°, respectively, while the dihedral angle between the two phenyl rings is 57.5 (2)°. The amino group is not involved in an N-H hydrogen bond. The crystal packing is established by inter-molecular C-H⋯O packing inter-actions involving a relatively rare weak three-center hydrogen bond between the keto O atom and H atoms of the two  ...[more]

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