Crystal structure of a methimazole-based ionic liquid.
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ABSTRACT:
SUBMITTER: Gaitor JC
PROVIDER: S-EPMC4719949 | biostudies-literature | 2015 Dec
REPOSITORIES: biostudies-literature
Publications
Crystal structure of a methimazole-based ionic liquid.
Gaitor Jamie C JC Zayas Manuel Sanchez MS Myrthil Darrel J DJ White Frankie F Hendrich Jeffrey M JM Sykora Richard E RE O'Brien Richard A RA Reilly John T JT Mirjafari Arsalan A
Acta crystallographica. Section E, Crystallographic communications 20151206 Pt 12
The structure of 1-methyl-2-(prop-2-en-1-ylsulfan-yl)-1H-imidazol-3-ium bromide, C7H11N2S(+)·Br(-), has monoclinic (P21/c) symmetry. In the crystal, the components are linked by N-H⋯Br and C-H⋯Br hydrogen bonds. The crystal structure of the title compound undeniably proves that methimazole reacts through the thione tautomer, rather than the thiol tautomer in this system. ...[more]
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