Ontology highlight
ABSTRACT:
SUBMITTER: Heindl C
PROVIDER: S-EPMC4762322 | biostudies-literature | 2016 Feb
REPOSITORIES: biostudies-literature
Heindl Claudia C Peresypkina Eugenia V EV Lüdeker David D Brunklaus Gunther G Virovets Alexander V AV Scheer Manfred M
Chemistry (Weinheim an der Bergstrasse, Germany) 20160119 8
The all-phosphorus analogue of benzene, stabilized as middle deck in triple-decker complexes, is a promising building block for the formation of graphene-like sheet structures. The reaction of [(CpMo)2 (μ,η(6) :η(6)-P6)] (1) with CuX (X=Br, I) leads to self-assembly into unprecedented 2D networks of [{(CpMo)2P6}(CuBr)4 ]n (2) and [{(CpMo)2 P6}(CuI)2]n (3). X-ray structural analyses show a unique deformation of the previously planar cyclo-P6 ligand. This includes bending of one P atom in an envel ...[more]