Ontology highlight
ABSTRACT:
SUBMITTER: Jin KJ
PROVIDER: S-EPMC4762874 | biostudies-literature | 2015 Nov
REPOSITORIES: biostudies-literature
Jin Kyoung Joo KJ Collum David B DB
Journal of the American Chemical Society 20151110 45
A combination of crystallographic, spectroscopic, and computational studies was applied to study the structures of lithium enolates derived from glycinimines of benzophenone and (+)-camphor. The solvents examined included toluene and toluene containing various concentrations of tetrahydrofuran, N,N,N',N'-tetramethylethylenediamine (TMEDA), (R,R)-N,N,N',N'-tetramethylcyclohexanediamine [(R,R)-TMCDA], and (S,S)-N,N,N',N'-tetramethylcyclohexanediamine [(S,S)-TMCDA]. Crystal structures show chelated ...[more]