Ontology highlight
ABSTRACT:
SUBMITTER: Reuillard B
PROVIDER: S-EPMC4794774 | biostudies-literature | 2016 Mar
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20160218 12
A freestanding H2-evolution electrode consisting of a copolymer-embedded cobaloxime integrated into a multiwall carbon nanotube matrix by π-π interactions is reported. This electrode is straightforward to assemble and displays high activity towards hydrogen evolution in near-neutral pH solution under inert and aerobic conditions, with a cobalt-based turnover number (TON(Co)) of up to 420. An analogous electrode with a monomeric cobaloxime showed less activity with a TON(Co) of only 80. These res ...[more]