Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Boundary lubrication of heterogeneous surfaces and the onset of cavitation in frictional contacts.

ABSTRACT: Surfaces can be slippery or sticky depending on surface chemistry and roughness. We demonstrate in atomistic simulations that regular and random slip patterns on a surface lead to pressure excursions within a lubricated contact that increase quadratically with decreasing contact separation. This is captured well by a simple hydrodynamic model including wall slip. We predict with this model that pressure changes for larger length scales and realistic frictional conditions can easily reach cavitation thresholds and significantly change the load-bearing capacity of a contact. Cavitation may therefore be the norm, not the exception, under boundary lubrication conditions.

SUBMITTER: Savio D

PROVIDER: S-EPMC4820388 | biostudies-literature | 2016 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Boundary lubrication of heterogeneous surfaces and the onset of cavitation in frictional contacts.

Savio Daniele D Pastewka Lars L Gumbsch Peter P

Science advances 20160325 3

Surfaces can be slippery or sticky depending on surface chemistry and roughness. We demonstrate in atomistic simulations that regular and random slip patterns on a surface lead to pressure excursions within a lubricated contact that increase quadratically with decreasing contact separation. This is captured well by a simple hydrodynamic model including wall slip. We predict with this model that pressure changes for larger length scales and realistic frictional conditions can easily reach cavitat ...[more]

PMID: 27051871

Similar Datasets

In-Liquid Lateral Force Microscopy of Micropatterned Surfaces in a Fatty Acid Solution under Boundary Lubrication.

Project description:This study aims to investigate the influence of surface morphology on boundary-lubricated friction in a stearic acid solution. The surface morphology was controlled by fabricating submicrometer line-and-space patterns on Si(100) surface via photolithography. The boundary-lubricated friction on the patterns was measured by in-liquid lateral force microscopy for both transverse and longitudinal ridges, with respect to the sliding direction; the highest friction was observed on longitudinal ridges and grooves, which is in agreement with the tendency observed in our previous friction studies on steel surfaces. To further investigate this phenomenon, some additional patterns having different submicrometer morphologies were prepared and their friction characteristics were investigated. On the patterns not allowing the fluid to flow along the grooves, the frictional forces were equivalent for transverse and longitudinal grooves and ridges. Therefore, the high friction observed on the longitudinal ridges was caused by flowing out of fluid along the grooves, and it was possible to conclude that the fluidity around the submicrometer ridges and grooves influences the friction-reducing effect of stearic acid in boundary lubrication regime.

| S-EPMC6811562 | biostudies-literature

Blurring the boundary between homogenous and heterogeneous catalysis using palladium nanoclusters with dynamic surfaces.

Project description:Using a magnetron sputtering approach that allows size-controlled formation of nanoclusters, we have created palladium nanoclusters that combine the features of both heterogeneous and homogeneous catalysts. Here we report the atomic structures and electronic environments of a series of metal nanoclusters in ionic liquids at different stages of formation, leading to the discovery of Pd nanoclusters with a core of ca. 2 nm surrounded by a diffuse dynamic shell of atoms in [C4C1Im][NTf2]. Comparison of the catalytic activity of Pd nanoclusters in alkene cyclopropanation reveals that the atomically dynamic surface is critically important, increasing the activity by a factor of ca. 2 when compared to compact nanoclusters of similar size. Catalyst poisoning tests using mercury and dibenzo[a,e]cyclooctene show that dynamic Pd nanoclusters maintain their catalytic activity, which demonstrate their combined features of homogeneous and heterogeneous catalysts within the same material. Additionally, kinetic studies of cyclopropanation of alkenes mediated by the dynamic Pd nanoclusters reveal an observed catalyst order of 1, underpinning the pseudo-homogeneous character of the dynamic Pd nanoclusters.

| S-EPMC8371125 | biostudies-literature

Partial-slip frictional response of rough surfaces.

Project description:If two elastic bodies with rough surfaces are first pressed against each other and then loaded tangentially, sliding will occur at the boundary of the contact area while the inner parts may still stick. With increasing tangential force, the sliding parts will expand while the sticking parts shrink and finally vanish. In this paper, we study the fractions of the contact area, tangential force and tangential stiffness, associated with the sticking portion of the contact area, as a function of the total applied tangential force up to the onset of full sliding. For the numerical analysis randomly rough, fractal surfaces are used, with the Hurst exponent H ranging from 0.1 to 0.9. Numerical simulations by boundary element method are compared with an analytical analysis in the framework of the Greenwood and Williamson (GW) model. In both cases, a universal linear dependency between the real contact area fraction in stick condition and the applied tangential force is found, regardless of the Hurst exponent of the rough surfaces. Regarding the dependence of the differential tangential stiffness on the tangential force, a linear relation is found in the GW case. For randomly rough surfaces, a nonlinear relation depending on H is derived.

| S-EPMC4046261 | biostudies-other

Long-lasting solid lubrication by CNT-coated patterned surfaces.

Project description:The use of lubricants (solid or liquid) is a well-known and suitable approach to reduce friction and wear of moving machine components. Another possibility to influence the tribological behaviour is the formation of well-defined surface topographies such as dimples, bumps or lattice-like pattern geometries by laser surface texturing. However, both methods are limited in their effect: surface textures may be gradually destroyed by plastic deformation and lubricants may be removed from the contact area, therefore no longer properly protecting the contacting surfaces. The present study focuses on the combination of both methods as an integral solution, overcoming individual limitations of each method. Multiwall carbon nanotubes (MWCNT), a known solid lubricant, are deposited onto laser surface textured samples by electrophoretic deposition. The frictional behaviour is recorded by a tribometer and resulting wear tracks are analysed by scanning electron microscopy and Raman spectroscopy in order to reveal the acting tribological mechanisms. The combined approach shows an extended, minimum fivefold longevity of the lubrication and a significantly reduced degradation of the laser textures. Raman spectroscopy proves decelerated MWCNT degradation and oxide formation in the contact. Finally, a lubricant entrapping model based on surface texturing is proposed and demonstrated.

| S-EPMC5314357 | biostudies-literature

Wetting and cavitation pathways on nanodecorated surfaces.

Project description:In this contribution we study the wetting and nucleation of vapor bubbles on nanodecorated surfaces via free energy molecular dynamics simulations. The results shed light on the stability of superhydrophobicity in submerged surfaces with nanoscale corrugations. The re-entrant geometry of the cavities under investigation is capable of sustaining a confined vapor phase within the surface roughness (Cassie state) both for hydrophobic and hydrophilic combinations of liquid and solid. The atomistic system is of nanometric size; on this scale thermally activated events can play an important role ultimately determining the lifetime of the Cassie state. Such a superhydrophobic state can break down by full wetting of the texture at large pressures (Cassie-Wenzel transition) or by nucleating a vapor bubble at negative pressures (cavitation). Specialized rare event techniques show that several pathways for wetting and cavitation are possible, due to the complex surface geometry. The related free energy barriers are of the order of 100kBT and vary with pressure. The atomistic results are found to be in semi-quantitative accord with macroscopic capillarity theory. However, the latter is not capable of capturing the density fluctuations, which determine the destabilization of the confined liquid phase at negative pressures (liquid spinodal).

| S-EPMC5159747 | biostudies-literature

Cavitation onset caused by acceleration.

Project description:Striking the top of a liquid-filled bottle can shatter the bottom. An intuitive interpretation of this event might label an impulsive force as the culprit in this fracturing phenomenon. However, high-speed photography reveals the formation and collapse of tiny bubbles near the bottom before fracture. This observation indicates that the damaging phenomenon of cavitation is at fault. Cavitation is well known for causing damage in various applications including pipes and ship propellers, making accurate prediction of cavitation onset vital in several industries. However, the conventional cavitation number as a function of velocity incorrectly predicts the cavitation onset caused by acceleration. This unexplained discrepancy leads to the derivation of an alternative dimensionless term from the equation of motion, predicting cavitation as a function of acceleration and fluid depth rather than velocity. Two independent research groups in different countries have tested this theory; separate series of experiments confirm that an alternative cavitation number, presented in this paper, defines the universal criteria for the onset of acceleration-induced cavitation.

| S-EPMC5559011 | biostudies-literature

Squeezing and stick-slip friction behaviors of lubricants in boundary lubrication.

Project description:The fundamental questions of how lubricant molecules organize into a layered structure under nanometers confinement and what is the interplay between layering and friction are still not well answered in the field of nanotribology. While the phase transition of lubricants during a squeeze-out process under compression is a long-standing controversial debate (i.e., liquid-like to solid-like phase transition versus amorphous glass-like transition), recent different interpretations to the stick-slip friction of lubricants in boundary lubrication present new challenges in this field. We carry out molecular dynamics simulations of a model lubricant film (cyclohexane) confined between molecularly smooth surfaces (mica)--a prototypical model system studied in surface force apparatus or surface force balance experiments. Through fully atomistic simulations, we find that repulsive force between two solid surfaces starts at about seven lubricant layers (n = 7) and the lubricant film undergoes a sudden liquid-like to solid-like phase transition at n < 6 monolayers thickness. Shear of solidified lubricant films at three- or four-monolayer thickness results in stick-slip friction. The sliding friction simulation shows that instead of shear melting of the film during the slip of the surface, boundary slips at solid-lubricant interfaces happen, while the solidified structure of the lubricant film is well maintained during repeated stick-slip friction cycles. Moreover, no dilation of the lubricant film during the slip is observed, which is surprisingly consistent with recent surface force balance experimental measurements.

| S-EPMC6042126 | biostudies-literature

Frictional behaviour of plant proteins in soft contacts: unveiling nanoscale mechanisms.

Project description:Despite the significance of nanotribology in the design of functional biomaterials, little is known about nanoscale friction in the presence of protein-coated soft contact surfaces. Here, we report a detailed investigation of frictional behaviour of sustainable plant proteins at the nanoscale for the first time, using deformable bio-relevant surfaces that achieve biologically relevant contact pressures. A combination of atomic force microscopy, quartz crystal microbalance with dissipation monitoring, and friction force microscopy with soft polydimethylsiloxane (PDMS, 150 kPa) surfaces was employed to elucidate the frictional properties of model plant proteins, i.e. lupine, pea, and potato proteins at the nanoscale while systematically varying the pH and ionic strength. Interactions of these plant proteins with purified mucins were also probed. We provide the much-needed direct experimental evidence that the main factor dictating the frictional properties of plant proteins is their affinity towards the surface, followed by the degree of protein film hydration. Proteins with high surface affinity, such as pea and potato protein, have better lubricating performance than lupine at the nanoscale. Other minor factors that drive lubrication are surface interactions between sliding bodies, especially at low load, whilst jamming of the contact area caused by larger protein aggregates increases friction. Novel findings reveal that interactions between plant proteins and mucins lead to superior lubricating properties, by combining high surface affinity from the plant proteins and high hydration by mucins. We anticipate that fundamental understanding gained from this work will set the stage for the design of a plethora of sustainable biomaterials and food with optimum nanolubrication performance.

| S-EPMC9926882 | biostudies-literature

Exploration on Aqueous Lubrication of Polymeric Microgels between Titanium Alloy Contacts.

Project description:Since titanium alloys have been widely used as joint replacement biomaterials, their superficial lubrication has evolved to be a critical factor for normal use. For this purpose, one kind of typical microgel, poly(NIPAAm-co-AA), was synthesized by emulsifier-free emulsion polymerization and used as an aqueous lubricating additive between titanium alloy contacts. The results show that the as-synthesized microgels reduced the coefficient of friction by 46% and the wear volume by 45%, compared with pure water. Meanwhile, due to their thermosensitive property, the microgels were employed as smart additives to modulate the interfacial friction, which was attributed to the transition of the hydrated state and the elastic deformation of microgel particles. To further dissect the lubrication mechanism, it was found that the lubricating property of microgels was substantially associated with the formation of a hydrated layer surrounding microgels, microbearing effect, interfacial adsorption, and the colloidal stability. Looking beyond, as one kind of soft colloidal lubricant, the microgels may play an important role in the biomedical metal lubrication.

| S-EPMC8638016 | biostudies-literature

Supramolecular synergy in the boundary lubrication of synovial joints.

Project description:Hyaluronan, lubricin and phospholipids, molecules ubiquitous in synovial joints, such as hips and knees, have separately been invoked as the lubricants responsible for the remarkable lubrication of articular cartilage; but alone, these molecules cannot explain the extremely low friction at the high pressures of such joints. We find that surface-anchored hyaluronan molecules complex synergistically with phosphatidylcholine lipids present in joints to form a boundary lubricating layer, which, with coefficient of friction μ≈0.001 at pressures to over 100 atm, has a frictional behaviour resembling that of articular cartilage in the major joints. Our findings point to a scenario where each of the molecules has a different role but must act together with the others: hyaluronan, anchored at the outer surface of articular cartilage by lubricin molecules, complexes with joint phosphatidylcholines to provide the extreme lubrication of synovial joints via the hydration-lubrication mechanism.

| S-EPMC4366511 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data