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Synthesis, Properties, and Design Principles of Donor-Acceptor Nanohoops.

ABSTRACT: We have synthesized a series of aza[8]cycloparaphenylenes containing one, two, and three nitrogens to probe the impact of nitrogen doping on optoelectronic properties and solid state packing. Alkylation of these azananohoops afforded the first donor-acceptor nanohoops where the phenylene backbone acts as the donor and the pyridinium units act as the acceptor. The impact on the optoelectronic properties was then studied experimentally and computationally to provide new insight into the effect of functionalization on nanohoops properties.

SUBMITTER: Darzi ER

PROVIDER: S-EPMC4827663 | biostudies-literature | 2015 Sep

REPOSITORIES: biostudies-literature

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Synthesis, Properties, and Design Principles of Donor-Acceptor Nanohoops.

Darzi Evan R ER Hirst Elizabeth S ES Weber Christopher D CD Zakharov Lev N LN Lonergan Mark C MC Jasti Ramesh R

ACS central science 20150903 6

We have synthesized a series of aza[8]cycloparaphenylenes containing one, two, and three nitrogens to probe the impact of nitrogen doping on optoelectronic properties and solid state packing. Alkylation of these azananohoops afforded the first donor-acceptor nanohoops where the phenylene backbone acts as the donor and the pyridinium units act as the acceptor. The impact on the optoelectronic properties was then studied experimentally and computationally to provide new insight into the effect of ...[more]

PMID: 27162989

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