Synthesis and optoelectronic properties of benzoquinone-based donor-acceptor compounds.

ABSTRACT: Herein, we report a mild and efficient palladium-catalyzed C-H functionalization method to synthesize a series of benzoquinone (BQ)-based charge-transfer (CT) derivatives in good yields. The optoelectronic properties of these compounds were explored both theoretically and experimentally and correlations to their structures were identified as a function of the nature and position of the donor group (meta and para) attached to the benzoquinone acceptor. Compound 3, where benzoquinone is para-conjugated to the diphenylamine donor group, exhibited thermally activated delayed fluorescence (TADF) with a biexponential lifetime characterized by a prompt ns component and a delayed component of 353 ?s.

SUBMITTER: Sutherland DR 

PROVIDER: S-EPMC6902851 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature