Ontology highlight
ABSTRACT:
SUBMITTER: Sutherland DR
PROVIDER: S-EPMC6902851 | biostudies-literature | 2019
REPOSITORIES: biostudies-literature
Beilstein journal of organic chemistry 20191204
Herein, we report a mild and efficient palladium-catalyzed C-H functionalization method to synthesize a series of benzoquinone (BQ)-based charge-transfer (CT) derivatives in good yields. The optoelectronic properties of these compounds were explored both theoretically and experimentally and correlations to their structures were identified as a function of the nature and position of the donor group (<i>meta</i> and <i>para</i>) attached to the benzoquinone acceptor. Compound <b>3</b>, where benzo ...[more]