Dataset Information

Transparent Films from CO2 -Based Polyunsaturated Poly(ether carbonate)s: A Novel Synthesis Strategy and Fast Curing.

ABSTRACT: Transparent films were prepared by cross-linking polyunsaturated poly(ether carbonate)s obtained by the multicomponent polymerization of CO2 , propylene oxide, maleic anhydride, and allyl glycidyl ether. Poly(ether carbonate)s with ABXBA multiblock structures were obtained by sequential addition of mixtures of propylene oxide/maleic anhydride and propylene oxide/allyl glycidyl ether during the polymerization. The simultaneous addition of both monomer mixtures provided poly(ether carbonate)s with AXA triblock structures. Both types of polyunsaturated poly(ether carbonate)s are characterized by diverse functional groups, that is, terminal hydroxy groups, maleate moieties along the polymer backbone, and pendant allyl groups that allow for versatile polymer chemistry. The combination of double bonds substituted with electron-acceptor and electron-donor groups enables particularly facile UV- or redox-initiated free-radical curing. The resulting materials are transparent and highly interesting for coating applications.

SUBMITTER: Subhani MA

PROVIDER: S-EPMC4850748 | biostudies-literature | 2016 Apr

REPOSITORIES: biostudies-literature

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Transparent Films from CO2 -Based Polyunsaturated Poly(ether carbonate)s: A Novel Synthesis Strategy and Fast Curing.

Subhani Muhammad Afzal MA Köhler Burkhard B Gürtler Christoph C Leitner Walter W Müller Thomas E TE

Angewandte Chemie (International ed. in English) 20160330 18

Transparent films were prepared by cross-linking polyunsaturated poly(ether carbonate)s obtained by the multicomponent polymerization of CO2 , propylene oxide, maleic anhydride, and allyl glycidyl ether. Poly(ether carbonate)s with ABXBA multiblock structures were obtained by sequential addition of mixtures of propylene oxide/maleic anhydride and propylene oxide/allyl glycidyl ether during the polymerization. The simultaneous addition of both monomer mixtures provided poly(ether carbonate)s with ...[more]

PMID: 27028458

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Project description:Carbon dioxide/epoxide copolymerization is an efficient way to add value to waste CO2 and to reduce pollution in polymer manufacturing. Using this process to make low molar mass polycarbonate polyols is a commercially relevant route to new thermosets and polyurethanes. In contrast, high molar mass polycarbonates, produced from CO2, generally under-deliver in terms of properties, and one of the most widely investigated, poly(cyclohexene carbonate), is limited by its low elongation at break and high brittleness. Here, a new catalytic polymerization process is reported that selectively and efficiently yields degradable ABA-block polymers, incorporating 6-23 wt % CO2. The polymers are synthesized using a new, highly active organometallic heterodinuclear Zn(II)/Mg(II) catalyst applied in a one-pot procedure together with biobased ?-decalactone, cyclohexene oxide, and carbon dioxide to make a series of poly(cyclohexene carbonate-b-decalactone-b-cyclohexene carbonate) [PCHC-PDL-PCHC]. The process is highly selective (CO2 selectivity >99% of theoretical value), allows for high monomer conversions (>90%), and yields polymers with predictable compositions, molar mass (from 38-71 kg mol-1), and forms dihydroxyl telechelic chains. These new materials improve upon the properties of poly(cyclohexene carbonate) and, specifically, they show good thermal stability (Td,5 ? 280 °C), high toughness (112 MJ m-3), and very high elongation at break (>900%). Materials properties are improved by precisely controlling both the quantity and location of carbon dioxide in the polymer chain. Preliminary studies show that polymers are stable in aqueous environments at room temperature over months, but they are rapidly degraded upon gentle heating in an acidic environment (60 °C, toluene, p-toluene sulfonic acid). The process is likely generally applicable to many other lactones, lactides, anhydrides, epoxides, and heterocumulenes and sets the scene for a host of new applications for CO2-derived polymers.

Dataset Information

Transparent Films from CO2 -Based Polyunsaturated Poly(ether carbonate)s: A Novel Synthesis Strategy and Fast Curing.

Publications

Transparent Films from CO2 -Based Polyunsaturated Poly(ether carbonate)s: A Novel Synthesis Strategy and Fast Curing.

Similar Datasets

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