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Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes.

ABSTRACT: The enantioselective, intermolecular hydroallylation of vinylarenes employing allylic phosphate electrophiles has been achieved through a copper hydride catalyzed process. The protocol described herein can be applied to a diverse set of vinylarene substrates and allows for the installation of the parent allyl group as well as a range of 2-substituted allylic fragments.

SUBMITTER: Wang YM 

PROVIDER: S-EPMC4851114 | biostudies-literature | 2016 Apr

REPOSITORIES: biostudies-literature

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Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes.

Wang Yi-Ming YM   Buchwald Stephen L SL  

Journal of the American Chemical Society 20160407 15

The enantioselective, intermolecular hydroallylation of vinylarenes employing allylic phosphate electrophiles has been achieved through a copper hydride catalyzed process. The protocol described herein can be applied to a diverse set of vinylarene substrates and allows for the installation of the parent allyl group as well as a range of 2-substituted allylic fragments. ...[more]

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