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Synthesis of Self-Assembled Multifunctional Nanocomposite Catalysts with Highly Stabilized Reactivity and Magnetic Recyclability.

ABSTRACT: In this paper, a multifunctional Fe3O4@SiO2@PEI-Au/Ag@PDA nanocomposite catalyst with highly stabilized reactivity and magnetic recyclability was synthesized by a self-assembled method. The magnetic Fe3O4 nanoparticles were coated with a thin layer of the SiO2 to obtain a negatively charged surface. Then positively charged poly(ethyleneimine) polymer (PEI) was self-assembled onto the Fe3O4@SiO2 by electrostatic interaction. Next, negatively charged glutathione capped gold nanoparticles (GSH-AuNPs) were electrostatically self-assembled onto the Fe3O4@SiO2@PEI. After that, silver was grown on the surface of the nanocomposite due to the reduction of the dopamine in the alkaline solution. An about 5?nm thick layer of polydopamine (PDA) was observed to form the Fe3O4@SiO2@PEI-Au/Ag@PDA nanocomposite. The Fe3O4@SiO2@PEI-Au/Ag@PDA nanocomposite was carefully characterized by the SEM, TEM, FT-IR, XRD and so on. The Fe3O4@SiO2@PEI-Au/Ag@PDA nanocomposite shows a high saturation magnetization (Ms) of 48.9?emu/g, which allows it to be attracted rapidly to a magnet. The Fe3O4@SiO2@PEI-Au/Ag@PDA nanocomposite was used to catalyze the reduction of p-nitrophenol (4-NP) to p-aminophenol (4-AP) as a model system. The reaction kinetic constant k was measured to be about 0.56?min(-1) (R(2)?=?0.974). Furthermore, the as-prepared catalyst can be easily recovered and reused for 8 times, which didn't show much decrease of the catalytic capability.

SUBMITTER: Yu X

PROVIDER: S-EPMC4857104 | biostudies-literature | 2016 May

REPOSITORIES: biostudies-literature

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Synthesis of Self-Assembled Multifunctional Nanocomposite Catalysts with Highly Stabilized Reactivity and Magnetic Recyclability.

Yu Xu X Cheng Gong G Zheng Si-Yang SY

Scientific reports 20160505

In this paper, a multifunctional Fe3O4@SiO2@PEI-Au/Ag@PDA nanocomposite catalyst with highly stabilized reactivity and magnetic recyclability was synthesized by a self-assembled method. The magnetic Fe3O4 nanoparticles were coated with a thin layer of the SiO2 to obtain a negatively charged surface. Then positively charged poly(ethyleneimine) polymer (PEI) was self-assembled onto the Fe3O4@SiO2 by electrostatic interaction. Next, negatively charged glutathione capped gold nanoparticles (GSH-AuNP ...[more]

PMID: 27147586

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Project description:The photonic propulsion of lightsails can be used to accelerate spacecraft to relativistic velocities, providing a feasible route for the exploration of interstellar space in the human lifetime. Breakthrough Starshot is an initiative aiming to launch lightsail-driven spacecrafts accelerated to a relativistic velocity of 0.2c via radiation pressure of a high-power laser beam in order to probe the habitable zone of Alpha Centauri, located 4.2 light years away from the Earth, and transmit back the scientific data collected in the flyby mission to an Earth-based receiver. The success of such a mission requires the lightsail to provide maximal acceleration while featuring beam-riding stability under the illumination of an intense laser beam during the launch phase. Moreover, the large-area lightsail can be harnessed to improve the margin in the photon-starved downlink channel throughout the communication phase by maximizing the gain of the transmitter despite extending the acceleration period and reducing the stability margin due to the elimination of a portion of the propulsion segments. Owing to the potential of metasurfaces to serve as low-weight versatile multifunctional photonic components, metasurface-based lightsails or metasails are deemed to be ideal candidates to simultaneously address the requirements of photonic propulsion and optical communication in laser-driven deep-space probes. Here, we demonstrate the design of a multifunctional metasail for providing high acceleration and enabling the self-stabilized beam-riding of a spacecraft with a detached payload from the sail while maximizing the transmission gain in the downlink optical communication. The metasail consists of two interleaved sub-arrays of dielectric unit cells operating based on the Pancharatnam-Berry geometric phase, optimized to meet the propulsion and communication requirements, respectively. The beam-riding stability of the sail is analyzed through simulation of the motion trajectory during the acceleration phase, while taking into account the effect of the relativistic Doppler shift, and the downlink communication performance is enabled by providing the required conjugate phase by the metasail elements, resulting in beam collimation. The obtained results verify the multifunctionality of the platform and point toward the promise of metasails for extended mission applications.

Dataset Information

Synthesis of Self-Assembled Multifunctional Nanocomposite Catalysts with Highly Stabilized Reactivity and Magnetic Recyclability.

Publications

Synthesis of Self-Assembled Multifunctional Nanocomposite Catalysts with Highly Stabilized Reactivity and Magnetic Recyclability.

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