Ontology highlight
ABSTRACT:
SUBMITTER: Albers L
PROVIDER: S-EPMC4891741 | biostudies-literature | 2016 Jun
REPOSITORIES: biostudies-literature
Albers Lena L Rathjen Saskia S Baumgartner Judith J Marschner Christoph C Müller Thomas T
Journal of the American Chemical Society 20160519 21
The installation of structural complex oligosilanes from linear starting materials by Lewis acid induced skeletal rearrangement reactions was studied under stable ion conditions. The produced cations were fully characterized by multinuclear NMR spectroscopy at low temperature, and the reaction course was studied by substitution experiments. The results of density functional theory calculations indicate the decisive role of attractive dispersion forces between neighboring trimethylsilyl groups fo ...[more]