Ontology highlight
ABSTRACT:
SUBMITTER: Xiao KJ
PROVIDER: S-EPMC4899946 | biostudies-literature | 2016 Feb
REPOSITORIES: biostudies-literature
Xiao Kai-Jiong KJ Chu Ling L Yu Jin-Quan JQ
Angewandte Chemie (International ed. in English) 20160122 8
Significant progress has been made in the past decade regarding the development of enantioselective C-H activation reactions by desymmetrization. However, the requirement for the presence of two chemically identical prochiral C-H bonds represents an inherent limitation in scope. Reported is the first example of kinetic resolution by a palladium(II)-catalyzed enantioselective C-H activation and C-C bond formation, thus significantly expanding the scope of enantioselective C-H activation reactions ...[more]