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Crystal structure of 1,4-bis-(3-ammonio-prop-yl)piperazine-1,4-diium bis-[dichromate(VI)].

ABSTRACT: The asymmetric unit of the organic-inorganic title salt, (C10H28N4)[Cr2O7]2, comprises one half of an 1,4-bis-(3-ammonio-prop-yl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO4 tetra-hedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N-H?O hydrogen bonds between the cations and anions and additional C-H?O inter-actions lead to the formation of a three-dimensional network structure.

SUBMITTER: Vetrivel S 

PROVIDER: S-EPMC4908532 | biostudies-literature | 2016 May

REPOSITORIES: biostudies-literature

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Crystal structure of 1,4-bis-(3-ammonio-prop-yl)piperazine-1,4-diium bis-[dichromate(VI)].

Vetrivel S S   Vinoth E E   Mullai R U RU   Aruljothi R R   NizamMohideen M M  

Acta crystallographica. Section E, Crystallographic communications 20160405 Pt 5

The asymmetric unit of the organic-inorganic title salt, (C10H28N4)[Cr2O7]2, comprises one half of an 1,4-bis-(3-ammonio-prop-yl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO4 tetra-hedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N-H⋯O hydrogen bonds  ...[more]

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