Unknown

Dataset Information

0

Crystal structure of trans-bis-(di-ethano-lamine-?(3) O,N,O')manganese(II) bis-(3-amino-benzoate).

ABSTRACT: Reaction of m-amino-benzoic acid (MABA), di-ethano-lamine (DEA) and MnCl2·4H2O led to the formation of the title salt, [Mn(C4H11NO2)2](C7H6NO2)2. In the complex cation, the Mn(2+) ion is located on an inversion centre and is coordinated by two symmetry-related tridentate DEA mol-ecules, leading to the formation of a slightly distorted MnN2O4 octa-hedron. The MABA(-) counter-anions are connected to the complex ion by a pair of rather strong O-H?O hydrogen bonds, yielding a 1:2 supra-molecular aggregate. Much weaker N-H?O hydrogen bonds connect neighbouring aggregates into a three-dimensional network structure.

SUBMITTER: Ibragimov AB 

PROVIDER: S-EPMC4910313 | biostudies-literature | 2016 Apr

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of trans-bis-(di-ethano-lamine-κ(3) O,N,O')manganese(II) bis-(3-amino-benzoate).

Ibragimov Aziz B AB   Zakirov Bakhtiyar S BS   Ashurov Jamshid M JM  

Acta crystallographica. Section E, Crystallographic communications 20160315 Pt 4

Reaction of m-amino-benzoic acid (MABA), di-ethano-lamine (DEA) and MnCl2·4H2O led to the formation of the title salt, [Mn(C4H11NO2)2](C7H6NO2)2. In the complex cation, the Mn(2+) ion is located on an inversion centre and is coordinated by two symmetry-related tridentate DEA mol-ecules, leading to the formation of a slightly distorted MnN2O4 octa-hedron. The MABA(-) counter-anions are connected to the complex ion by a pair of rather strong O-H⋯O hydrogen bonds, yielding a 1:2 supra-molecular agg  ...[more]

Similar Datasets

Unknown Crystal structure of bis-(tri-ethano-lamine-?(3) N,O,O')nickel(II) bis-(3-hy-droxy-benzoate) tetra-hydrate.
| S-EPMC4908535 | biostudies-other
Unknown Crystal structure of trans-di-aqua-bis-(nicotinamide-?N (1))bis-(4-nitro-benzoato-?O)manganese(II).
| S-EPMC4908509 | biostudies-literature
Unknown Crystal structure of trans-dihydrido-bis[tris-(di-methyl-amino)-phosphane-?P]platinum(II).
| S-EPMC4438795 | biostudies-literature
Unknown Crystal structure of bis-{?-2-[bis-(2-hy-droxy-eth-yl)amino]-ethano-lato}bis-(?-3,5-di-methyl-pyrazolato)tricopper(II) dibromide sesquihydrate.
| S-EPMC7534225 | biostudies-literature
Unknown Crystal structure of bis[4-(di-methyl-amino)-pyridinium] bis(2-nitro-benzoate) trihydrate.
| S-EPMC4257197 | biostudies-literature
Unknown Crystal structure of bis-[4-(di-methyl-amino)-pyridine-κN (1)]bis-(methanol-κO)bis-(thio-cyanato-κN)manganese(II).
| S-EPMC4420091 | biostudies-literature
Unknown Crystal structure of di-ethano-lbis(thio-cyanato)-bis(urotropine)cobalt(II) and tetra-ethano-lbis(thio-cyanato)-cobalt(II)-urotropine (1/2).
| S-EPMC8739191 | biostudies-literature
Unknown Crystal structure of <i>trans</i>-bis-[2-(1<i>H</i>-benzotriazol-1-yl)acetato-?<i>O</i>]bis-(ethano-lamine-?<sup>2</sup> <i>N</i>,<i>O</i>)copper(II).
| S-EPMC6362665 | biostudies-literature
Unknown catena-Poly[[trans-bis-(1,3-benzo-thia-zole-?N)manganese(II)]-di-?-chlorido].
| S-EPMC4120608 | biostudies-literature
Unknown trans-Bis(acetato-?O)diaquabis-(2-amino-pyrazine-?N)manganese(II) dihydrate.
| S-EPMC3212198 | biostudies-literature