Unknown

Dataset Information

0

Trans-2,5-Di-methyl-piperazine-1,4-diium bis(perchlorate) dihydrate: crystal structure and Hirshfeld surface analysis.

ABSTRACT: The asymmetric unit of the title hydrated mol-ecular salt, C6H16N2 (2+)·2ClO4 (-)·2H2O, contains a half dication (completed by inversion symmetry), a perchlorate anion and a water mol-ecule. The extended structure consists of infinite chains of formula [(ClO4)H2O] n (n) (-) ions extending along the b axis linked by Ow-H?O (w = water) hydrogen bonds. These chains are cross-linked by the dications via N-H?Ow and weak C-H?O hydrogen bonds, thus forming a three-dimensional supra-molecular network. Three-dimensional Hirshfeld surface analysis and two-dimensional fingerprint maps reveal that the structure is dominated by H?O/O?H and H?H contacts.

SUBMITTER: Ben Mleh C 

PROVIDER: S-EPMC4910334 | biostudies-literature | 2016 Apr

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

trans-2,5-Di-methyl-piperazine-1,4-diium bis(perchlorate) dihydrate: crystal structure and Hirshfeld surface analysis.

Ben Mleh Cherifa C   Roisnel Thierry T   Marouani Houda H  

Acta crystallographica. Section E, Crystallographic communications 20160331 Pt 4

The asymmetric unit of the title hydrated mol-ecular salt, C6H16N2 (2+)·2ClO4 (-)·2H2O, contains a half dication (completed by inversion symmetry), a perchlorate anion and a water mol-ecule. The extended structure consists of infinite chains of formula [(ClO4)H2O] n (n) (-) ions extending along the b axis linked by Ow-H⋯O (w = water) hydrogen bonds. These chains are cross-linked by the dications via N-H⋯Ow and weak C-H⋯O hydrogen bonds, thus forming a three-dimensional supra-molecular network. T  ...[more]

Similar Datasets

Unknown trans-2,5-Di-methyl-piperazine-1,4-diium dinitrate.
| S-EPMC4051050 | biostudies-literature
Unknown Piperazine-1,4-diium bis-(perchlorate) dihydrate.
| S-EPMC3007905 | biostudies-other
Unknown 1-Benzyl-piperazine-1,4-diium bis-(perchlorate) monohydrate.
| S-EPMC3006781 | biostudies-literature
Unknown 1,4-Dimethyl-piperazine-1,4-diium bis-(hexa-fluoro-phosphate) dihydrate.
| S-EPMC3344619 | biostudies-literature
Unknown Crystal structure and Hirshfeld surface analysis of <i>trans</i>-2,5-di-methyl-piperazine-1,4-diium tetra-chlorido-cobaltate(II).
| S-EPMC8025852 | biostudies-literature
Unknown Piperazine-1,4-diium bis-[tetra-chlorido-aurate(III)] dihydrate.
| S-EPMC2971124 | biostudies-literature
Unknown Piperazine-1,4-diium bis-(2,4,5-tricarb-oxy-benzoate) dihydrate.
| S-EPMC3629622 | biostudies-literature
Unknown Bis[1-(2,3-di-methyl-phen-yl)piperazine-1,4-diium] bis-(oxonium) cyclo-hexa-phosphate dihydrate.
| S-EPMC3770409 | biostudies-literature
Unknown Bis(1-benzyl-piperazine-1,4-diium) hexa-chloridocadmate(II) dihydrate.
| S-EPMC3007331 | biostudies-literature
Unknown 1,4-Dimethyl-piperazine-1,4-diium dibromide dihydrate.
| S-EPMC3379296 | biostudies-literature