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Piperazine-1,4-diium bis-[tetra-chlorido-aurate(III)] dihydrate.

ABSTRACT: In the title compound, (C(4)H(12)N(2))[AuCl(4)](2)·2H(2)O, the Au(III) atom has a square-planar geometry. The piperazinium dication lies on an inversion centre and adopts a typical chair conformation. In the crystal, a combination of N-H?O, N-H?Cl and O-H?Cl hydrogen bonds results in the formation of a three-dimensional network.

SUBMITTER: Polishchuk AV

PROVIDER: S-EPMC2971124 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Piperazine-1,4-diium bis-[tetra-chlorido-aurate(III)] dihydrate.

Polishchuk Anna V AV Karaseva Emilia T ET Pushilin Mikhail A MA

Acta crystallographica. Section E, Structure reports online 20091017 Pt 11

In the title compound, (C(4)H(12)N(2))[AuCl(4)](2)·2H(2)O, the Au(III) atom has a square-planar geometry. The piperazinium dication lies on an inversion centre and adopts a typical chair conformation. In the crystal, a combination of N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds results in the formation of a three-dimensional network. ...[more]

PMID: 21578127

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