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Fabricating of high-performance functional graphene fibers for micro-capacitive energy storage.


ABSTRACT: Although graphene is a typical two dimensional materials, it has converted to multi-dimensional materials with many unique properties. As an example, the one dimensional graphene fiber is fabricated by utilizing ionic liquid as coagulation and functional diamines as cross-linkers to connect graphene oxide layers. The fibers show excellent mechanical properties and superior electrical performance. The tensile strength of the resultant fibers reaches ~729?MPa after a super high temperature thermal annealing treatment at 2800?°C. Additionally, quasi-solid-state flexible micro-capacitors are fabricated with promising result on energy storage. The device show a specific volumetric capacity as high as ~225?F/cm(3) (measured at 103.5?mA cm(-3) in a three-electrode cell), as well as a long cycle life of 2000 times. The initial results indicate that these fibers will be a good candidate to replace energy storage devices for miniaturized portable electronic applications.

SUBMITTER: Fan T 

PROVIDER: S-EPMC4937368 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature

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Fabricating of high-performance functional graphene fibers for micro-capacitive energy storage.

Fan Tianju T   Zhao Chunyan C   Xiao Zhuangqing Z   Guo Fangjun F   Cai Kaiyu K   Lin Hai H   Liu Yidong Y   Meng Hong H   Min Yong Y   Epstein Arthur J AJ  

Scientific reports 20160708


Although graphene is a typical two dimensional materials, it has converted to multi-dimensional materials with many unique properties. As an example, the one dimensional graphene fiber is fabricated by utilizing ionic liquid as coagulation and functional diamines as cross-linkers to connect graphene oxide layers. The fibers show excellent mechanical properties and superior electrical performance. The tensile strength of the resultant fibers reaches ~729 MPa after a super high temperature thermal  ...[more]

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