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RbZnFe(PO4)2: synthesis and crystal structure.

ABSTRACT: A new iron phosphate, rubidium zinc iron(III) phosphate, RbZnFe(PO4)2, has been synthesized as single crystals by the flux method. This compound is isostructural to the previously reported KCoAl(PO4)2 [Chen et al. (1997 ?). Acta Cryst. C53,1754-1756]. Its structure consists of a three-dimensional framework built up from corner-sharing PO4 and (Zn,Fe)O4 tetra-hedra. This mode of linkage forms channels parallel to the [100], [010] and [001] directions in which the Rb(+) ions are located.

SUBMITTER: Badri A

PROVIDER: S-EPMC4971844 | biostudies-literature | 2016 Aug

REPOSITORIES: biostudies-literature

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RbZnFe(PO4)2: synthesis and crystal structure.

Badri Abdessalem A Ben Amara Mongi M

Acta crystallographica. Section E, Crystallographic communications 20160707 Pt 8

A new iron phosphate, rubidium zinc iron(III) phosphate, RbZnFe(PO4)2, has been synthesized as single crystals by the flux method. This compound is isostructural to the previously reported KCoAl(PO4)2 [Chen et al. (1997 ▸). Acta Cryst. C53,1754-1756]. Its structure consists of a three-dimensional framework built up from corner-sharing PO4 and (Zn,Fe)O4 tetra-hedra. This mode of linkage forms channels parallel to the [100], [010] and [001] directions in which the Rb(+) ions are located. ...[more]

PMID: 27536385

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