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Europium (III) Organic Complexes in Porous Boron Nitride Microfibers: Efficient Hybrid Luminescent Material.


ABSTRACT: We report the design and synthesis of a novel kind of organic-inorganic hybrid material via the incorporation of europium (III) ?-diketonate complexes (Eu(TTA)3, TTA?=?2-thenoyltrifluoroacetone) into one-dimensional (1D) porous boron nitride (BN) microfibers. The developed Eu(TTA)3@BN hybrid composites with typical 1D fibrous morphology exhibit bright visible red-light emission on UV illumination. The confinement of Eu(TTA)3 within pores of BN microfibers not only decreases the aggregation-caused quenching in solid Eu(TTA)3, but also improves their thermal stabilities. Moreover, The strong interactions between Eu(TTA)3 and porous BN matrix result in an interesting energy transfer process from BN host to TTA ligand and TTA ligand to Eu3+ ions, leading to the remarkable increase of red emission. The synthetic approach should be a very promising strategy which can be easily expanded to other hybrid luminescent materials based on porous BN.

SUBMITTER: Lin J 

PROVIDER: S-EPMC5043355 | biostudies-literature | 2016 Sep

REPOSITORIES: biostudies-literature

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Europium (III) Organic Complexes in Porous Boron Nitride Microfibers: Efficient Hybrid Luminescent Material.

Lin Jing J   Feng Congcong C   He Xin X   Wang Weijia W   Fang Yi Y   Liu Zhenya Z   Li Jie J   Tang Chengchun C   Huang Yang Y  

Scientific reports 20160930


We report the design and synthesis of a novel kind of organic-inorganic hybrid material via the incorporation of europium (III) β-diketonate complexes (Eu(TTA)<sub>3</sub>, TTA = 2-thenoyltrifluoroacetone) into one-dimensional (1D) porous boron nitride (BN) microfibers. The developed Eu(TTA)<sub>3</sub>@BN hybrid composites with typical 1D fibrous morphology exhibit bright visible red-light emission on UV illumination. The confinement of Eu(TTA)<sub>3</sub> within pores of BN microfibers not onl  ...[more]

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