Unknown

Dataset Information

0

Crystal structure of trans-di-aqua-bis-(4-cyano-benzoato-?O)bis-(N,N-di-ethyl-nicotinamide-?N)zinc(II).

ABSTRACT: In the title complex, [Zn(C8H4NO2)2(C10H14N2O)2(H2O)2], the ZnII cation, located on an inversion centre, is coordinated by two water mol-ecules, two 4-cyano-benzoate (CB) anions and two di-ethyl-nicotinamide (DENA) ligands in a distorted N2O4 octa-hedral geometry. In the mol-ecule, the dihedral angle between the planar carboxyl-ate group and the adjacent benzene ring is 9.50?(14)°, while the benzene and pyridine rings are oriented at a dihedral angle of 56.99?(5)°. The water mol-ecules exhibit both an intra-molecular hydrogen bond [to the non-coordinating carboxyl-ate O atom, enclosing an S(6) hydrogen-bonding motif, where O?O = 2.6419?(19)?Å] and an inter-molecular hydrogen bond [to the amide carbonyl O atom, enclosing an R22(16) ring motif, where O?O = 2.827?(2)?Å]; the latter lead to the formation of supra-molecular chains propagating along the [110] direction.

SUBMITTER: Akduran N 

PROVIDER: S-EPMC5050756 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of <i>trans</i>-di-aqua-bis-(4-cyano-benzoato-κ<i>O</i>)bis-(<i>N</i>,<i>N</i>-di-ethyl-nicotinamide-κ<i>N</i>)zinc(II).

Akduran Nurcan N   Necefoğlu Hacali H   Aydoğdu Ömer Ö   Hökelek Tuncer T  

Acta crystallographica. Section E, Crystallographic communications 20160905 Pt 10

In the title complex, [Zn(C<sub>8</sub>H<sub>4</sub>NO<sub>2</sub>)<sub>2</sub>(C<sub>10</sub>H<sub>14</sub>N<sub>2</sub>O)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>], the Zn<sup>II</sup> cation, located on an inversion centre, is coordinated by two water mol-ecules, two 4-cyano-benzoate (CB) anions and two di-ethyl-nicotinamide (DENA) ligands in a distorted N<sub>2</sub>O<sub>4</sub> octa-hedral geometry. In the mol-ecule, the dihedral angle between the planar carboxyl-ate group and the adjacent  ...[more]

Similar Datasets

Unknown Crystal structure of trans-di-aqua-bis-(4-cyano-benzoato-?O)bis-(nicotinamide-?N (1))cobalt(II).
| S-EPMC4420108 | biostudies-literature
Unknown Crystal structure of <i>trans</i>-di-aqua-bis-(4-cyano-benzoato-?<i>O</i>)bis-(<i>N</i>,<i>N</i>-di-ethyl-nicotinamide-?<i>N</i>)cadmium.
| S-EPMC5137619 | biostudies-literature
Unknown Crystal structure of trans-di-aqua-bis-(nicotinamide-?N (1))bis-(4-nitro-benzoato-?O)manganese(II).
| S-EPMC4908509 | biostudies-literature
Unknown Crystal structure of di-aqua-bis-(N,N-di-ethyl-nicotinamide-?N (1))bis-(2,4,6-tri-methyl-benzoato-?O (1))cobalt(II).
| S-EPMC4910347 | biostudies-literature
Unknown Aqua-bis-(3-chloro-benzoato-?O)bis-(N,N-di-ethyl-nicotinamide-?N)copper(II).
| S-EPMC3793693 | biostudies-literature
Unknown Crystal structure and Hirshfeld surface analysis of di-aqua-bis-(N,N-di-ethyl-nicotinamide-κN1)bis-(2,4,6-tri-methyl-benzoato-κO)manganese(II).
| S-EPMC5946959 | biostudies-literature
Unknown Crystal structure of catena-poly[[aqua-bis-(4-cyano-benzoato-?O)copper(II)]-?-N,N-di-ethyl-nicotinamide-?(2) N (1):O].
| S-EPMC4971868 | biostudies-other
Unknown Crystal structure of tri-aqua-(4-cyano-benzoato-?(2) O,O')(nicotinamide-?N (1))zinc 4-cyano-benzoate.
| S-EPMC4459300 | biostudies-other
Unknown trans-Bis(2-acet-amido-5-methyl-benzoato-κO)tetra-aqua-zinc.
| S-EPMC3089096 | biostudies-literature
Unknown Di-?-nicotinamide-?N:O;?O:N-bis-[aqua-bis-(4-bromo-benzoato)-?O;?O,O'-manganese(II)].
| S-EPMC3212190 | biostudies-literature