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Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ²N,N')silver(I) tri-fluoro-methane-sulfonate.

ABSTRACT: The title compound, [Ag(qPyr)₂]CF₃SO₃ where qPyr = 1-(quinoline-2-yl-methyl-ene)amino-pyrene, C₂₆H₁₆N₂, was synthesized from a reaction of silver tri-fluoro-methane-sulfonate and qPyr in di-chloro-methane-methanol mixed media. In this design, the qPyr ligand was chosen for its characteristic excitation and emission profiles, which could enable the tracking of the silver complex within biological targets. The Ag^I atom resides in a distorted tetra-hedral N₄ coordination sphere. Analysis of the packing pattern revealed significant intra- and inter-molecular π-π stacking inter-actions between the [Ag(qPyr)₂]⁺ cations. In addition, a weak C-H⋯O hydrogen bond consolidates the packing between cations and anions.

SUBMITTER: Pinto M

PROVIDER: S-EPMC5050784 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature

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Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ2N,N')silver(I) tri-fluoro-methane-sulfonate.

Pinto Miguel M Chakraborty Indranil I Mascharak Pradip P

Acta crystallographica. Section E, Crystallographic communications 20160930 Pt 10

The title compound, [Ag(qPyr)2]CF3SO3 where qPyr = 1-(quinoline-2-yl-methyl-ene)amino-pyrene, C26H16N2, was synthesized from a reaction of silver tri-fluoro-methane-sulfonate and qPyr in di-chloro-methane-methanol mixed media. In this design, the qPyr ligand was chosen for its characteristic excitation and emission profiles, which could enable the tracking of the silver complex within biological targets. The AgI atom re ...[more]

PMID: 27746949

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