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The Dependency of Nematic and Twist-bend Mesophase Formation on Bend Angle.

ABSTRACT: We have prepared and studied a family of cyanobiphenyl dimers with varying linking groups with a view to exploring how molecular structure dictates the stability of the nematic and twist-bend nematic mesophases. Using molecular modelling and 1D ¹H NOESY NMR spectroscopy, we determine the angle between the two aromatic core units for each dimer and find a strong dependency of the stability of both the nematic and twist-bend mesophases upon this angle, thereby satisfying earlier theoretical models.

SUBMITTER: Mandle RJ

PROVIDER: S-EPMC5098182 | biostudies-literature | 2016 Nov

REPOSITORIES: biostudies-literature

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The Dependency of Nematic and Twist-bend Mesophase Formation on Bend Angle.

Mandle Richard J RJ Archbold Craig T CT Sarju Julia P JP Andrews Jessica L JL Goodby John W JW

Scientific reports 20161107

We have prepared and studied a family of cyanobiphenyl dimers with varying linking groups with a view to exploring how molecular structure dictates the stability of the nematic and twist-bend nematic mesophases. Using molecular modelling and 1D <sup>1</sup>H NOESY NMR spectroscopy, we determine the angle between the two aromatic core units for each dimer and find a strong dependency of the stability of both the nematic and twist-bend mesophases upon this angle, thereby satisfying earlier theoret ...[more]

PMID: 27819300

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