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Twist-Bend Stage in the Relaxation of Sheared Chiral Nematic Suspensions of Cellulose Nanocrystals.

ABSTRACT: Aqueous suspensions of cellulose nanocrystals (CNCs), prepared from natural cellulose by sulfuric acid hydrolysis, form stable chiral nematic suspensions above a critical CNC concentration. The chiral nematic organization may be preserved in films prepared from the suspensions by evaporation. However, shrinkage, gelation, and shear during film formation impair the optical properties of the dry film. In this article, we report an unusual behavior for a sample in which gelation occurred before the sample reached iridescent pitch values. In attempting to decouple changes in texture due to evaporation from those due to shear relaxation effects for this sample, we observed a transitory nematic-like texture that was induced by shear during the preparation of the sample for polarized light microscopy. We propose that the transition between chiral nematic and nematic structures involves a twist-bend-like intermediate and not an untwisting of the chiral nematic phase.

SUBMITTER: Gray DG

PROVIDER: S-EPMC6641273 | biostudies-literature | 2016 Aug

REPOSITORIES: biostudies-literature

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Twist-Bend Stage in the Relaxation of Sheared Chiral Nematic Suspensions of Cellulose Nanocrystals.

Gray Derek G DG Mu Xiaoyue X

ACS omega 20160818 2

Aqueous suspensions of cellulose nanocrystals (CNCs), prepared from natural cellulose by sulfuric acid hydrolysis, form stable chiral nematic suspensions above a critical CNC concentration. The chiral nematic organization may be preserved in films prepared from the suspensions by evaporation. However, shrinkage, gelation, and shear during film formation impair the optical properties of the dry film. In this article, we report an unusual behavior for a sample in which gelation occurred before the ...[more]

PMID: 31457126

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