Ionic Liquid Ordering at an Oxide Surface.

ABSTRACT: The interaction of the ionic liquid [C₄ C₁ Im][BF₄ ] with anatase TiO₂ , a model photoanode material, has been studied using a combination of synchrotron radiation photoelectron spectroscopy and near-edge X-ray absorption fine structure spectroscopy. The system is of interest as a model for fundamental electrolyte-electrode and dye-sensitized solar cells. The initial interaction involves degradation of the [BF₄ ]^- anion, resulting in incorporation of F into O?vacancies in the anatase surface. At low coverages, [C₄ C₁ Im][BF₄ ] is found to order at the anatase(101) surface via electrostatic attraction, with the imidazolium ring oriented 32±4° from the anatase TiO₂ surface. As the coverage of ionic liquid increases, the influence of the oxide surface on the topmost layers is reduced and the ordering is lost.

SUBMITTER: Wagstaffe M 

PROVIDER: S-EPMC5129479 | biostudies-literature | 2016 Nov

REPOSITORIES: biostudies-literature