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Smart Organic Two-Dimensional Materials Based on a Rational Combination of Non-covalent Interactions.


ABSTRACT: Rational design of organic 2D (O2D) materials has made some progress, but it is still in its infancy. A class of self-assembling small molecules is presented that form nano/microscale supramolecular 2D materials in aqueous media. A judicial combination of four different intermolecular interactions forms the basis for the robust formation of these ultrathin assemblies. These assemblies can be programmed to disassemble in response to a specific protein and release its non-covalently bound guest molecules.

SUBMITTER: Bai W 

PROVIDER: S-EPMC5154734 | biostudies-literature | 2016 Aug

REPOSITORIES: biostudies-literature

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Smart Organic Two-Dimensional Materials Based on a Rational Combination of Non-covalent Interactions.

Bai Wei W   Jiang Ziwen Z   Ribbe Alexander E AE   Thayumanavan S S  

Angewandte Chemie (International ed. in English) 20160804 36


Rational design of organic 2D (O2D) materials has made some progress, but it is still in its infancy. A class of self-assembling small molecules is presented that form nano/microscale supramolecular 2D materials in aqueous media. A judicial combination of four different intermolecular interactions forms the basis for the robust formation of these ultrathin assemblies. These assemblies can be programmed to disassemble in response to a specific protein and release its non-covalently bound guest mo  ...[more]

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