Highly energetic phenomena in water electrolysis.

ABSTRACT: Water electrolysis performed in microsystems with a fast change of voltage polarity produces optically invisible nanobubbles containing H₂ and O₂ gases. In this form the gases are able to the reverse reaction of water formation. Here we report extreme phenomena observed in a millimeter-sized open system. Under a frequency of driving pulses above 100?kHz the process is accompanied by clicking sounds repeated every 50?ms or so. Fast video reveals that synchronously with the click a bubble is growing between the electrodes which reaches a size of 300??m in 50??s. Detailed dynamics of the system is monitored by means of a vibrometer by observing a piece of silicon floating above the electrodes. The energy of a single event is estimated as 0.3??J and a significant part of this energy is transformed into mechanical work moving the piece. The observations are explained by the combustion of hydrogen and oxygen mixture in the initial bubble with a diameter of about 40??m. Unusual combustion mechanism supporting spontaneous ignition at room temperature is responsible for the process. The observed effect demonstrates a principal possibility to build a microscopic internal combustion engine.

SUBMITTER: Postnikov AV 

PROVIDER: S-EPMC5159792 | biostudies-literature |

REPOSITORIES: biostudies-literature