Ontology highlight
ABSTRACT:
SUBMITTER: Faizi DJ
PROVIDER: S-EPMC5166982 | biostudies-literature | 2016 Nov
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20161013 46
The first ring-forming thioboration reaction of C-C π bonds is reported. This catalyst-free method proceeds in the presence of a commercially available external electrophilic boron source (B-chlorocatecholborane) in good to high yields. The method is scalable and tolerates a variety of functional groups that are intolerant of other major borylation methods. The resulting borylated benzothiophenes participate in a variety of in situ derivatization reactions, showcasing that these borylated interm ...[more]