Sintering-Resistant Nanoparticles in Wide-Mouthed Compartments for Sustained Catalytic Performance.

ABSTRACT: Particle sintering is one of the most significant impediments to functional nanoparticles in many valuable applications especially catalysis. Herein, we report that sintering-resistant nanoparticle systems can be realized through a simple materials-design which maximizes the particle-to-particle traveling distance of neighbouring nanoparticles. As a demonstration, Pt nanoparticles were placed apart from each other in wide-mouthed compartments tailored on the surface of self-assembled silica nanosheets. These Pt nanoparticles retained their particle size after calcination at elevated temperatures because the compartment wall elongates the particle-to-particle traveling distance to preclude the possibility of sintering. Moreover, these Pt nanoparticles in wide-mouthed compartments were fully

SUBMITTER: Liu J 

PROVIDER: S-EPMC5290533 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature