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Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth-oxy-2-oxo-ethyl-idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo-hex-2-enyl-idene]hydrazinyl-idene}-4-oxo-thia-zolidin-3-yl)fumarate.

ABSTRACT: The crystal structure and the conformation of the title compound, C22H27N3O7S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thia-zolidinone derivative prepared and isolated as pure product from thio-semicarbazone carvone. The mol-ecule is built up from an oxo-thia-zolidine ring tetra-substituted by a meth-oxy-oxo-ethyl-idene, a maleate, an oxygen and a cyclo-hexyl-idene-hydrazone. The cyclo-hexyl-idene ring is statistically disordered over two positions, resulting in an inversion of configuration for the substituted carbon.

SUBMITTER: N'ait Ousidi A 

PROVIDER: S-EPMC5290585 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of dimethyl 2-((2<i>Z</i>,5<i>Z</i>)-5-(2-meth-oxy-2-oxo-ethyl-idene)-2-{(<i>E</i>)-[2-methyl-5-(prop-1-en-2-yl)cyclo-hex-2-enyl-idene]hydrazinyl-idene}-4-oxo-thia-zolidin-3-yl)fumarate.

N'ait Ousidi Abdellah A   Ait Itto My Youssef MY   Auhmani Aziz A   Riahi Abdelkhalek A   Auhmani Abdelwahed A   Daran Jean-Claude JC  

Acta crystallographica. Section E, Crystallographic communications 20170131 Pt 2

The crystal structure and the conformation of the title compound, C<sub>22</sub>H<sub>27</sub>N<sub>3</sub>O<sub>7</sub>S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thia-zolidinone derivative prepared and isolated as pure product from thio-semicarbazone carvone. The mol-ecule is built up from an oxo-thia-zolidine ring tetra-substituted by a meth-oxy-oxo-ethyl-idene, a maleate, an oxygen and a cyclo-hexyl-idene-hydrazone. The cyclo-hexyl-idene ring  ...[more]

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