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Metal-organic frameworks for H2 and CH4 storage: insights on the pore geometry-sorption energetics relationship.

ABSTRACT: This study aims to assess the possibility of improving H2 and CH4 binding affinity to the aromatic walls of a designed new Metal-Organic Framework (MOF) through simultaneous dispersive interactions. It is suggested here that desirable H2 and CH4 storage media at low pressures require narrow uniform pores associated with large surface area, a trade-off that is challenging to achieve.

SUBMITTER: Alkordi MH 

PROVIDER: S-EPMC5330523 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

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Metal-organic frameworks for H<sub>2</sub> and CH<sub>4</sub> storage: insights on the pore geometry-sorption energetics relationship.

Alkordi Mohamed H MH   Alkordi Mohamed H MH   Belmabkhout Youssef Y   Cairns Amy A   Eddaoudi Mohamed M  

IUCrJ 20170210 Pt 2

This study aims to assess the possibility of improving H<sub>2</sub> and CH<sub>4</sub> binding affinity to the aromatic walls of a designed new Metal-Organic Framework (MOF) through simultaneous dispersive interactions. It is suggested here that desirable H<sub>2</sub> and CH<sub>4</sub> storage media at low pressures require narrow uniform pores associated with large surface area, a trade-off that is challenging to achieve. ...[more]

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