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Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity.


ABSTRACT: We realized that tailoring the pore size/geometry and chemistry, by virtue of alkynyl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm3 (STP) cm-3 at 298 K and 5-80 bar.

SUBMITTER: Shao K 

PROVIDER: S-EPMC7953312 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature

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Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity.

Shao Kai K   Pei Jiyan J   Wang Jia-Xin JX   Yang Yu Y   Cui Yuanjing Y   Zhou Wei W   Yildirim Taner T   Li Bin B   Chen Banglin B   Qian Guodong G  

Chemical communications (Cambridge, England) 20190904 76


We realized that tailoring the pore size/geometry and chemistry, by virtue of alkynyl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm<sup>3</sup> (STP) cm<sup>-3</sup> at 298 K and 5-80 bar. ...[more]

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