Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity.
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ABSTRACT:
SUBMITTER: Shao K
PROVIDER: S-EPMC7953312 | biostudies-literature | 2019 Sep
REPOSITORIES: biostudies-literature
Publications
Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity.
Shao Kai K Pei Jiyan J Wang Jia-Xin JX Yang Yu Y Cui Yuanjing Y Zhou Wei W Yildirim Taner T Li Bin B Chen Banglin B Qian Guodong G
Chemical communications (Cambridge, England) 20190904 76
We realized that tailoring the pore size/geometry and chemistry, by virtue of alkynyl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm<sup>3</sup> (STP) cm<sup>-3</sup> at 298 K and 5-80 bar. ...[more]
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