The Ferraquinone-Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity.
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ABSTRACT:
SUBMITTER: Dauth A
PROVIDER: S-EPMC5330656 | biostudies-literature | 2017 Feb
REPOSITORIES: biostudies-literature
Publications
The Ferraquinone-Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity.
Dauth Alexander A Gellrich Urs U Diskin-Posner Yael Y Ben-David Yehoshoa Y Milstein David D
Journal of the American Chemical Society 20170213 7
A ferraquinone-ferrahydroquinone organometallic redox couple was prepared and characterized. Intricate cooperativity of the metal was observed with different positions on the ligand. This allowed cooperative activation of small molecules like molecular hydrogen, oxygen, and bromine. Likewise, dehydrogenation of alcohols was achieved through 1,6 metal-ligand cooperation. ...[more]
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