Ontology highlight
ABSTRACT:
SUBMITTER: Cheng HG
PROVIDER: S-EPMC5362052 | biostudies-literature | 2017 Feb
REPOSITORIES: biostudies-literature
Cheng Hong-Gang HG Miguélez Javier J Miyamura Hiroyuki H Yoo Woo-Jin WJ Kobayashi Shū S
Chemical science 20161005 2
A new class of chiral bifunctional heterogeneous materials composed of Au/Pd nanoparticles and chiral phosphoric acids as active orthogonal catalysts was prepared by utilizing a facile pseudo-suspension co-polymerization method. It was found that this heterogeneous catalyst was capable of facilitating the sequential aerobic oxidation-asymmetric intramolecular aza-Friedel-Crafts reaction between benzyl alcohols and <i>N</i>-aminoethylpyrroles. Moreover, the designed chiral heterogeneous catalyst ...[more]