Ontology highlight
ABSTRACT:
SUBMITTER: Morshedi M
PROVIDER: S-EPMC5380882 | biostudies-literature | 2017 Apr
REPOSITORIES: biostudies-literature
Morshedi Mahbod M Thomas Michael M Tarzia Andrew A Doonan Christian J CJ White Nicholas G NG
Chemical science 20170216 4
The interaction of tetratopic amidinium-containing receptors with terephthalate anions leads to porous framework materials assembled through charge-assisted hydrogen bonds. The frameworks form in good yield within minutes in water at room temperature, but no framework material is obtained if other anions (Cl<sup>-</sup>, Br<sup>-</sup>, NO<sub>3</sub><sup>-</sup>, SO<sub>4</sub><sup>2-</sup> or isophthalate<sup>2-</sup>) are used in place of terephthalate. Two forms of the framework can be prepa ...[more]