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Crystal structure of bis-(1,10-phenanthroline-?2N,N')(1,3-thia-zole-2-thiol-ato-?2S2,N)nickel(II) hexa-fluorido-phosphate 1,4-dioxane sesquisolvate.

ABSTRACT: The title salt, [Ni(C3H2NS2)(C12H8N2)2]PF6·1.5C4H8O2, was the unexpected product on making an attempt to prepare an [Ni(2-mercapto-thia-zol-ate)(1,10-phenanthroline)]+ complex by reaction of [NiCl2(1,10-phen-an-throline)] with 2-mercapto-thia-zolate. In the resulting complex, the 2-mercapto-thia-zolate anion acts as a chelating ligand, which coordinates to the NiII ion with the thia-zolyl N and thiol-ate S atoms. In the crystal, ?-? stacking inter-actions between the coordinating 1,10-phenanthroline mol-ecules of adjacent complexes result in a zigzag chain running parallel to the c axis. Weak C-H?X (X = O, F) hydrogen-bonding inter-actions between the chains and 1,4-dioxane solvent mol-ecules and PF6- counter-anions lead to the formation of sheets parallel to the ac plane.

SUBMITTER: Kai K 

PROVIDER: S-EPMC5382628 | biostudies-literature | 2017 Apr

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(1,10-phenanthroline-κ<sup>2</sup><i>N</i>,<i>N</i>')(1,3-thia-zole-2-thiol-ato-κ<sup>2</sup><i>S</i><sup>2</sup>,<i>N</i>)nickel(II) hexa-fluorido-phosphate 1,4-dioxane sesquisolvate.

Kai Keisuke K   Hamaguchi Tomohiko T   Ando Isao I  

Acta crystallographica. Section E, Crystallographic communications 20170324 Pt 4

The title salt, [Ni(C<sub>3</sub>H<sub>2</sub>NS<sub>2</sub>)(C<sub>12</sub>H<sub>8</sub>N<sub>2</sub>)<sub>2</sub>]PF<sub>6</sub>·1.5C<sub>4</sub>H<sub>8</sub>O<sub>2</sub>, was the unexpected product on making an attempt to prepare an [Ni(2-mercapto-thia-zol-ate)(1,10-phenanthroline)]<sup>+</sup> complex by reaction of [NiCl<sub>2</sub>(1,10-phen-an-throline)] with 2-mercapto-thia-zolate. In the resulting complex, the 2-mercapto-thia-zolate anion acts as a chelating ligand, which coordinates t  ...[more]

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