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Crystal structures of the polymer precursors 3-(2,5-dimeth-oxy-3,4,6-tri-methyl-phen-yl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxo-cyclo-hexa-1,4-dien-yl)propyl methacrylate.


ABSTRACT: The closely related title compounds, 3-(2,5-dimeth-oxy-3,4,6-tri-methyl-phen-yl)propyl methacrylate, C18H26O4 (I), and 3-(2,4,5-trimethyl-3,6-dioxo-cyclo-hexa-1,4-dien-yl)propyl methacrylate, C16H20O4 (II), are monomers suitable for the preparation of redox polymers. They consist of a propyl-methacrylate group and three methyl substituents on di-meth-oxy-benzene and quinone cores, respectively. Both crystal structures feature weak C-H?O hydrogen bonds and C-H??(ring) contacts between methyl groups and the six-membered rings.

SUBMITTER: Goswami SK 

PROVIDER: S-EPMC5418778 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature

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Crystal structures of the polymer precursors 3-(2,5-dimeth-oxy-3,4,6-tri-methyl-phen-yl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxo-cyclo-hexa-1,4-dien-yl)propyl methacrylate.

Goswami Shailesh K SK   Hanton Lyall R LR   McAdam C John CJ   Moratti Stephen C SC   Simpson Jim J  

Acta crystallographica. Section E, Crystallographic communications 20170404 Pt 5


The closely related title compounds, 3-(2,5-dimeth-oxy-3,4,6-tri-methyl-phen-yl)propyl methacrylate, C<sub>18</sub>H<sub>26</sub>O<sub>4</sub> (I), and 3-(2,4,5-trimethyl-3,6-dioxo-cyclo-hexa-1,4-dien-yl)propyl methacrylate, C<sub>16</sub>H<sub>20</sub>O<sub>4</sub> (II), are monomers suitable for the preparation of redox polymers. They consist of a propyl-methacrylate group and three methyl substituents on di-meth-oxy-benzene and quinone cores, respectively. Both crystal structures feature weak  ...[more]

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