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Crystal structure of 2-cyano-3,3-bis-(ethyl-sulfan-yl)-N-o-tolyl-acryl-amide.

ABSTRACT: In the mol-ecule of the title compound, C15H18N2OS2, the central S2C=C(CN)C moiety is planar (r.m.s. deviation = 0.029?Å). The C=O and C-CN groups are trans to each other across their common C-C bond. In the crystal, one classical and two 'weak' hydrogen bonds combine with borderline N?N and S?S contacts to form layers parallel to (10-2). One ethyl group is disordered over two positions with relative occupancy 0.721/0.279?(7).

SUBMITTER: Azzam RA

PROVIDER: S-EPMC5418798 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature

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Crystal structure of 2-cyano-3,3-bis-(ethyl-sulfan-yl)-N-o-tolyl-acryl-amide.

Azzam Rasha A RA Elgemeie Galal H GH Ramadan Rokia R Jones Peter G PG

Acta crystallographica. Section E, Crystallographic communications 20170428 Pt 5

In the mol-ecule of the title compound, C15H18N2OS2, the central S2C=C(CN)C moiety is planar (r.m.s. deviation = 0.029 Å). The C=O and C-CN groups are trans to each other across their common C-C bond. In the crystal, one classical and two 'weak' hydrogen bonds combine with borderline N⋯N and S⋯S contacts to form layers parallel to (10-2). One ethyl group is disordered over two positions with relative occupancy 0.721/0.279 (7). ...[more]

PMID: 28529790

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