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3,3-Bis[(4-chloro-phen-yl)sulfan-yl]-1-methyl-piperidin-2-one.

ABSTRACT: The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86?(13) and 46.94?(11)°]. In the crystal, C-H?O inter-actions link the mol-ecules into [010] supra-molecular chains with a helical topology. C-H?Cl and C-H?? inter-actions are also present.

SUBMITTER: Zukerman-Schpector J

PROVIDER: S-EPMC3007065 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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3,3-Bis[(4-chloro-phen-yl)sulfan-yl]-1-methyl-piperidin-2-one.

Zukerman-Schpector Julio J De Simone Carlos A CA Olivato Paulo R PR Cerqueira Carlos R CR Santos Jean M M JM Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100630 Pt 7

The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)°]. In the crystal, C-H⋯O inter-actions link the mol-ecules into [010] supra-molecular chains with a helical topology. C-H⋯Cl and C-H⋯π inter-actions are also present. ...[more]

PMID: 21588060

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