Ontology highlight
ABSTRACT:
SUBMITTER: Bivaud S
PROVIDER: S-EPMC4464414 | biostudies-literature | 2015
REPOSITORIES: biostudies-literature
Bivaud Sébastien S Goeb Sébastien S Croué Vincent V Allain Magali M Pop Flavia F Sallé Marc M
Beilstein journal of organic chemistry 20150605
The synthesis of a new Pd coordination-driven self-assembled ring M6L3 constructed from a concave tetrapyridyl π-extended tetrathiafulvalene ligand (exTTF) is described. The same ligand is also able to self-assemble in a M4L2 mode as previously described. Herein, we demonstrate that the bulkiness of the ancillary groups in the Pd complex allows for modulating the size and the shape of the resulting discrete self-assembly, which therefore incorporate two (M4L2) or three (M6L3) electroactive exTTF ...[more]