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Versatile control of the submolecular motion of di(acylamino)pyridine-based [2]rotaxanes.


ABSTRACT: A cyclic network of chemical reactions has been conceived for exchanging the dynamic behaviour of di(acylamino)pyridine-based rotaxanes and surrogates. X-ray diffraction studies revealed the intercomponent interactions in these interlocked compounds and were consistent with those found in solution by dynamic NMR experiments. This particular binding site was incorporated into a molecular shuttle enabled for accessing two states with an outstanding positional discrimination through chemical manipulation. Furthermore, the ability of the di(acylamino)pyridine domain to associate with external binders with a complementary array of HB donor and acceptor sites was exploited for the advance of an unprecedented electrochemical switch operating through a reversible anion radical recognition process.

SUBMITTER: Martinez-Cuezva A 

PROVIDER: S-EPMC5490047 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature

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Versatile control of the submolecular motion of di(acylamino)pyridine-based [2]rotaxanes.

Martinez-Cuezva Alberto A   Pastor Aurelia A   Cioncoloni Giacomo G   Orenes Raul-Angel RA   Alajarin Mateo M   Symes Mark D MD   Berna Jose J  

Chemical science 20150318 5


A cyclic network of chemical reactions has been conceived for exchanging the dynamic behaviour of di(acylamino)pyridine-based rotaxanes and surrogates. X-ray diffraction studies revealed the intercomponent interactions in these interlocked compounds and were consistent with those found in solution by dynamic NMR experiments. This particular binding site was incorporated into a molecular shuttle enabled for accessing two states with an outstanding positional discrimination through chemical manipu  ...[more]

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