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Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols.

ABSTRACT: In this paper we report an efficient and mild procedure for the conversion of organic thiocyanates to thiols in the presence of phosphorus pentasulfide (P₂S₅) in refluxing toluene. The method avoids the use of expensive and hazardous transition metals and harsh reducing agents, as required by reported methods, and provides an attractive alternative to the existing methods for the conversion of organic thiocyanates to thiols.

SUBMITTER: Maurya CK

PROVIDER: S-EPMC5496577 | biostudies-literature | 2017

REPOSITORIES: biostudies-literature

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Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols.

Maurya Chandra Kant CK Mazumder Avik A Gupta Pradeep Kumar PK

Beilstein journal of organic chemistry 20170620

In this paper we report an efficient and mild procedure for the conversion of organic thiocyanates to thiols in the presence of phosphorus pentasulfide (P<sub>2</sub>S<sub>5</sub>) in refluxing toluene. The method avoids the use of expensive and hazardous transition metals and harsh reducing agents, as required by reported methods, and provides an attractive alternative to the existing methods for the conversion of organic thiocyanates to thiols. ...[more]

PMID: 28694864

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