High Pressure Spectroscopic Investigation on Proton Transfer in Squaric Acid and 4,4'-Bipyridine Co-crystal.

ABSTRACT: In attempt to the obtain detailed geometric information of proton transfer compound (subsequently denote as SQBP) formed between squaric acid (SQ)and 4,4'-bipyridine(BP), and to investigate the mechanisms of pressure-induced double proton transfer and related structural phase transition, we carried out in-situ high pressure Raman spectroscopy of SQBP up to 20 GPa. A solid-solid phase transition together with double proton transfer phenomenon was confirmed by Raman spectroscopy at about 1.5 GPa, and the activation of C?=?O stretching mode in Raman spectra indicates a square-ring structure of SQ with four symmetric C?=?O bond formation. These results are further supported by first-principals calculations and in-situ high pressure infrared absorption spectroscopy. Additionally, Raman intensity analysis suggests that a higher-order phase transition with planar BP molecular structure occurred in the pressure range of 3~6?GPa. As a result, the ? electron delocalization effect in BP dominated the intensity enhancement of C?=?O stretching mode in SQ. To the best of our knowledge, this is the first time observation of the intensity enhancement of proton donor's normal modes induced by proton acceptor's ? electron delocalization.

SUBMITTER: Ma Z 

PROVIDER: S-EPMC5498627 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature